Repositório do LNEG
National Laboratory of Energy and Geology Scientific Repository
Recent Submissions
Fire-resistant materials: characterization and thermal behavior of intumescent gels for fire resistant glass [Poster]
Publication . Donato, Mariana; Esteves, M. Alexandra; Capelo, Anabela; Oliveira, Fernando; Ferreira, Cristina; Alves, Isabel N.; Morgado, Vanessa; Correia, Jose B.; Teixeira, Jennifer P.; Oliveira Fernandes, Carolina; Silva, Ricardo Magno Lopes; Rocha, Jorge; Salomé, Pedro; Cunha Diamantino, Teresa; Barreiros, Maria Alexandra
Lithium Role in the Clean Energy Transition: Challenges and Prospects [Comunicação oral]
Publication . Almeida, Joana; Pedrosa, Fátima; Plancha, Maria João; Gonçalves, Ana; Nogueira, Carlos
The materials of historical monuments: characterisation of the mortars of the Roman aqueduct of Zaghouan-Carthage
Publication . Carvalho, Fernanda; Lima, Maria Margarida Rolim Augusto; Silva, Teresa; Veiga, João Pedro
ABSTRACT: The Zaghouan-Carthage Roman aqueduct was the largest built by the Roman Empire at the time, and its archaeological remains bear witness to the excellence of Roman construction. Its importance over the centuries makes it a unique case study for characterising the different types of mortar used. This work aims to study these materials, considering their functions, especially as structural elements or as render, to relate the chemical and mineralogical characteristics observed to both the function and historical context of the monument. Using a multi-analytical approach, the preservation of samples was prioritised whenever possible. The results indicate that mortars with a structural function have higher silicon contents than those used as render. In the case of water conduit coatings, the mortars were formulated with ground ceramics to develop hydraulic properties and ensure the waterproofing material. However, it was not possible to identify a characteristic pattern related to the historical construction periods.
Ediacaran and early-palaeozoic bimodal volcanism in the Ossa-Morena Zone, SW Iberian Massif: New clues for intraplate rifting shortly after the Cadomian Orogeny
Publication . Cachapuz, P.; Chichorro, Martim Afonso; Bento dos Santos, Telmo; Carvalho, D.; Linnemann, Ulf; Zieger-Hofmann, M.; Zieger, J.; Dantas, E.; Santos, R. V.; Moita, Patrícia; Beltrame, M.; Solá, A. Rita; Díaz-Azpíroz, M.; Fernández, C.
ABSTRACT: This study focuses on bimodal meta-volcanic rocks present in the Iberian Massif, in the Evora-Aracena Metamorphic Belt of the Ossa-Morena Zone (OMZ), near the boundary with the South Portuguese Zone. New petrological, geochemical (whole-rock and Sr-Nd isotopes) and LA-ICP-MS U-Pb zircon geochronology data are presented to track the magmatic evolution of both felsic and mafic rocks and their respective geodynamic setting during the transition between the Cadomian Orogeny and subsequent Palaeozoic rifting events. Our research shows that the Evora-Aracena Metamorphic Belt (EAMB) in the southwestern OMZ possesses a significant record of the transition between the Cadomian and Variscan cycles. U-Pb geochronological data confirm the existence of both felsic and mafic Ediacaran igneous rocks (546 and 556 Ma, respectively), a novelty in the region. The Cadomian-related felsic rocks show geochemical similarities to meta-felsic rocks formed during the initial phases of the Cambrian rifting event, namely very negative epsilon Nd values (-10.1 to -11.8), depleted HREE patterns and orogenic signatures. Such similarities imply that meta-felsic rocks formed in the earliest stages of the Cambrian Rift-to-Drift event resulted from a shallower melting. Moreover, meta-felsic rocks formed in the early stages of the Cambrian rifting (525 Ma) present a significant amount of Ediacaran aged zircons, whereas the Cadomian-related counterparts display a few discordant Cambrian ages, likely a consequence of Pb-loss. This indicates that the convergent, subduction-related regime that prevailed during most of the Cryogenian-Ediacaran times along the boundaries of NW Gondwana was swiftly supplanted by a rift-dominated regime during the Cambrian, with no substantial gap between these two thermal events. Meanwhile, meta-felsic rocks formed during the Rift-to-Drift (525-480 Ma) event exhibit progressively higher epsilon Nd values (-5.0 to +3.0), HREE-enrichment, as well as anorogenic signatures, denoting an increasing contribution of mantle-derived melts. This increasing mantle contribution eventually led to the occurrence of bimodal magmatism in the Middle Cambrian Main Rift event. Such Cambrian mafic rocks, unlike the Ediacaran mafic rocks that present flat REE patterns and continental arc signatures, display varying degrees of LREE enrichment and N-MORB to E-MORB signatures.
Pre-Mesoproterozoic crustal framework and Mesoproterozoic evolution of the SW Angolan Shield: structural, geochemical, and isotopic insights from the Kunene Complex and surrounding basement
Publication . Merino-Martínez, E.; Ferreira, Ezequiel; Valverde-Vaquero, Pablo; Rodrigues, José Feliciano; Escuder-Viruete, Javier; Garcia-Lobon, Jose Luis; Beranoaguirre, Aratz; Feria, María Carmen; Rey-Moral, Carmen; Silva, Paulo Bravo; González-Cuadra, Pablo; Sousa, João Carlo; Potti, Julián; Máximo, J.; Gutiérrez-Medina, M.; Gumiel, J.C.; Galán, Gustavo; Mochales, Tania; Manuel, José; Cordeiro, Domingos; Tassinari, Colombo C. G.; Montero, P.; Sato, Kei; Fuenlabrada, José Manuel; Galindo, Carmen
ABSTRACT: The southwestern Angolan Shield hosts the Earth's largest Mesoproterozoic massif-type anorthosite complex (up to 53,500 km(2)), the Kunene Complex (KC). This complex is the result of a long-lived (similar to 200 Ma) episodic emplacement of coalescent magmatic pulses. The recent acquisition of multidisciplinary data during the PLANAGEO project has significantly enhanced our understanding of the Precambrian crustal framework from the southwestern Angolan Shield. Combined multi-isotope, structural and geophysical data reveals distinctive crustal zones in the southwestern Angolan Shield that clearly influenced KC's emplacement within a back-arc setting. The spatio-temporal arrangement of KC pulses suggests westwards magma migration within a complex contractional regime involving large strike-slip systems. A long-lasting and extensive accretionary orogen was responsible for the tectono-thermal activity recorded during most of the Mesoproterozoic. Crustal thinning and partial melting of isotopically heterogeneous lower-crustal sources through mantle upwelling promoted the episodic felsic magmatism contemporaneous with the KC. Crustal contamination processes are evident in gabbroanorthosites, indicating mantle metasomatism and interaction with wall-rocks and granite melts during ascent, upwelled by lateral-driven forces. Deposition of extensive metasedimentary sequences (<1.26 Ga) covering the KC, along with 1.23-1.07 Ga sublithospheric and mantle-derived magmatism, indicate a shift from a compressional to an extensional regime during late-Mesoproterozoic times. Regional correlations with other Mesoproterozoic units in African and Brazilian counterparts suggest a shared geological evolution, despite potential differences in tectonic setting. These findings supports a refined geological model for the Mesoproterozoic evolution of the southwestern part of the Congo Craton.