Relvas, F.Morais, Ana Rita C.Lukasik, Rafal M.2016-03-142016-03-142015Relvas, F.; Morais, A.R.; Bogel-Lukasik, R. - Selective hydrolysis of wheat straw hemicellulose using high-pressure CO2 as catalyst. In: RSC Advances, 2015, Vol. 5, p. 73935-739442046-2069http://hdl.handle.net/10400.9/2882The processing of wheat straw using high-pressure CO2–H2O technology was studied with the objective to evaluate the effect of CO2 as catalyst on the hydrothermal production of hemicellulose-derived sugars either as oligomers or as monomers. Also, the reduction of the crystallinity of the cellulose-rich fraction was assessed. Over a range of reaction conditions (0 to 50 bar of initial CO2 pressure and 0 to 45 minutes of holding time, at T ¼ 180 C), the addition of CO2 to water-based processes led to the in situ formation of carbonic acid, which allowed us to obtain a higher dissolution of wheat straw hemicellulose. Furthermore, this approach led to a xylo-oligosaccharide (XOS) rich fraction, yielding 79.6 g of XOS per 100 g of the initial xylan content (at 50 bar of initial CO2 pressure and 12 min of residence time) while the water-only process gave only 70.8 g of XOS per 100 g of initial xylan content. Furthermore, for higher pressures of CO2, a decrease in oligosaccharide content was found and was counterbalanced by production of monomer sugars, achieving a maximum of 5.7 g L1 at the severest condition.engHydrolysisLignocellulosic residuesHemicelluloseWheat Strawjournal article10.1039/c5ra14632a