Browsing by Author "Mata, Ana C."
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- Green chemistry and biorefineries: common future?Publication . Carvalho, V.; Relvas, F.; Lopes, André; Morais, Ana Rita C.; Silva, Sara P. Magalhães da; Mata, Ana C.; Roseiro, Luisa B.; Lukasik, Rafal M.Green Chemistry and Biorefinery concepts are two approaches helping to develop new and more sustainable processes.The implementation of both methodologies impels to fossil-independent future with bioeconomy based on natural feedstock like biowaste and industrial by-products. The development of technologies for valorisation of these resources is a key role of society in the creation of sustainable and more environmentally friendly future. Shortly after the Rio Declaration on Environment and Development, Anastas and Warner presented 12 Principles of Green Chemistry but more a decade before Trevor Kletz in his Jubilee lecture entitled “What you don’t have, can’t leak” draw the frames in which scientific and industrial work should be performed. This basis of green chemistry created a fundament for further development and implementation of Anastas and Warner principles of green chemistry. One of these frames is integration of green chemistry principles in the biorefinery concept. The biorefinery is an industrial facility (or network of facilities) that cover an extensive range of combined technologies aiming to full sustainable transformation of biomass into their building blocks with the concomitant production of biofuels, energy, chemicals and materials, preferably of value added products. One of the principles of green chemistry is the use of more sustainable solvents. Some examples of them are ionic liquids (ILs) and supercritical fluids (scF). This work will demonstrate the successful examples of lignocellulosic biomass valorisation using green solvents answering the question regarding the feasibility of future biorefineries made in a greener manner.
- Integrated conversion of agroindustrial residue with high pressure CO2 within the biorefinery conceptPublication . Morais, Ana Rita C.; Mata, Ana C.; Lukasik, Rafal M.Sustainable production of energy and other added-value products from biomass-derived polysaccharides is a key challenge of an efficient biorefinery facility. Most technologies for biomass processing are energy demanding and use significant amounts of chemicals and catalysts. The need to develop a process which is devoid of all these shortcomings associated with conventional processes is emphasized. A new approach is demonstrated for an integrated wheat straw biorefinery using a green technology, highpressure CO2–H2O, to produce oligosaccharides from hemicellulose fraction and to enhance the cellulose digestibility for the enzymatic hydrolysis. Over the range of reaction conditions (130, 215, 225 °C and 0 to 54 bar of CO2), CO2 adds value to the process by in situ formation of carbonic acid that leads to higher dissolution of hemicellulose into xylo-oligosaccharides and xylose and to the use of less energy in comparison with water-only technologies. Without an additional chemical catalyst, high-pressure CO2–H2O out performed hydrothermal reactions and gave much higher total sugars yield for wheat straw (as high as 84% in comparison with 67.4% with auto-hydrolysis at a 10 °C higher temperature). Apart from the results obtained for valorisation of hemicellulose fraction, both chemical and physical effects of CO2 coupled to enzymatic hydrolysis resulted in a glucan conversion to glucose yield of 82%, which consists of 26% improvement over those obtained during auto-hydrolysis. The influence of the high pressure reaction on the processed solid was examined by spectroscopic methods (namely Scanning Electron Microscopy and Fourier Transform Infrared Spectroscopy). The obtained results suggest that the high pressure CO2-based method is a very promising alternative technology allowing integrated biomass processing within the biorefinery concept.