Browsing by Author "Varela, Francisco"
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- Benefits and drawbacks of energetic valorisation of Eucalyptus Globulus stumps by thermochemical processesPublication . Pinto, Filomena; Andre, Rui N.; Lopes, Helena; Neves, Diogo; Varela, Francisco; Santos, João Navalho; Miranda, Migueln the pulp and paper industry in Iberian Peninsula there is an intensive use of eucalyptus globulus that has a fast growth and a high productivity. There are large areas of forest dedicated to its growth. After 9 to 12 year rotation cycles trees are cut and the stumps are left in the fields. After 2 or 3 harvesting cycles these tree stumps are removed from the fields and considered low value biomass wastes. This corresponds to depletion on organic matter and of valuable minerals related to soil fertility. The use of these biomass wastes in thermochemical conversion processes like gasification or combustion may be a valuable alternative solution as it allows taking profit of these wastes energetic content. The solid by-products obtained by thermal conversion (ashes) may be incorporated in soils to return the valuable minerals and to ensure a good forest management system. Stumps removed from eucalyptus stands were used in combustion trials to improve the burning conditions and in gasification tests with different experimental conditions to obtain syngas suitable to be used in furnaces (chemical recover) of pulp industries. Stumps combustion and gasification processes were compared in terms of stumps energetic valorisation, gaseous emissions and gasification gas utilisation.
- Comparison of co-gasification of wastes mixtures obtained from rice production wastes using air or oxygenPublication . Pinto, Filomena; Andre, Rui N.; Lopes, Helena; Neves, Diogo; Varela, Francisco; Santos, João Navalho; Miranda, MiguelThe world annual production of rice is higher than 700.7 million tons, which generates rice husk and straw wastes. Rice culture also produces big amounts of polyethylene (PE) bags used in rice packs and for seeds and fertilizer storage that usually end up in landfills, due to their degree of contamination. The energetic valorisation of these wastes may be accomplished by different processes, co-gasification is one of the most viable, as it leads to the production of a synthetic gaseous mixture (bio-syngas) that can be used for energy production to be used during rice milling processes. Gasification of rice husks has some challenges, due to these wastes high content of silica and alkali metals that lead to the formation of solids with lower melting point, thus, leading to bed agglomeration that causes reactor erosion and serious damage. PE has lower ash content and much higher energetic content than rice husks. However, PE polymeric structure may lead to the formation of higher tar contents, which compromise most gasification gas utilisations. Co-gasification of PE and rice husks allows taking advantages of each waste favourable characteristic, diluting the unsuitable features. Co-gasification of these wastes was done in presence of steam blended with air or oxygen. Steam promoted the gasification reactions and favoured H2 production. Air or oxygen promoted the partial oxidation of the feedstocks to be co-gasified and supplied the energy necessary for the endothermic gasification reactions. The use of air has a low cost, but has the great disadvantage of diluting the bio-syngas produced, thus lowering its energetic content. On the other hand, the use of oxygen solves the problems related to gas dilution with nitrogen, but increases the operating cost. Bio-syngas composition obtained by co-gasification trials done with air enriched with different oxygen contents was compared with those obtained with air or pure oxygen to determine the best approach considering both the technical and economical sustainability.
- Hydrothermal liquefaction of biomass produced from domestic sewage treatment in high-rate pondsPublication . De Aguiar Do Couto, Eduardo; Pinto, Filomena; Varela, Francisco; Reis, Alberto; Costa, Paula; Calijuri, Maria LuciaABSTRACT: This study evaluates the application of biomass produced from the treatment of domestic sewage in high-rate ponds (HRPs) as feedstock for the production of bio-oil via hydrothermal liquefaction (HTL). The effects of reaction time, temperature, and biomass/water ratio on the yield of bio-oil were assessed. In addition, a balance of carbon and nitrogen among the products (bio-oil, aqueous phase, solid residue, and gas) was carried out, in order to evaluate the quality of the bio-oil and possibilities for increasing value from the byproducts. In a 15-min operation at 300 degrees C with biomass/water ratio of 1/10 (w.w(-1)), the bio-oil yield was of 44.4% (Dry Ash Free - daf-basis). Under every condition tested, the solid residue was the most abundant byproduct, mostly due to the high ash content in the biomass. The minimum nitrogen recovery in the bio-oil was 57%, obtained in the operation at 275 degrees C, which is considered the main disadvantage of the process. The use of biomass directly after its production may result in an excessive consumption of energy due to the high water content. However, the need for drying is reduced when compared to other microalgal-based bioenergy production processes, potentially achieving a positive energy balance in the HTL.
- Production of bio-hydrocarbons by hydrotreating of pomace oilPublication . Pinto, Filomena; Varela, Francisco; Gonçalves, Maria Margarida; Andre, Rui N.; Costa, Paula; Mendes, BenildeOlive pomace oil is a by-product from the olive oil industry that is still being used in the food industry as a low value vegetable oil. Crude olive pomace oil needs to be refined and is blended with virgin olive oils before being used as edible oil. The detection of toxic compounds led to more restricted legislation and to the search of alternative valorisation processes, such as hydrotreating to obtain bio-hydrocarbons. Hydrotreating of olive pomace oil at moderate temperatures (from 300 to 430 C) and in presence of initial hydrogen pressure of 1.1 MPa led to triglycerides destruction and to their conversion into a large range of organic compounds with predominance to hydrocarbons. Even without any catalyst, conversions into hydrocarbons were always higher than 90% (v/v). Catalyst presence, such as: CoMo/Al2O3, FCC (fluid catalytic cracking) or HZSM-5 changed hydrogenated liquids composition. The highest content of alkanes was obtained with CoMo catalyst, while FCC and HZSM-5 led to the highest contents of aromatic compounds. The results obtained showed that olive pomace oil can be efficiently converted into bio-hydrocarbons with a wide range of applications. It was also studied the effect of pyrolysing olive pomace oil prior to its hydrotreating. Pyrolysis pre-treatment seems to have favoured hydrotreating process by promoting initial cracking reactions. Thus, it was possible to increase the production of liquid compounds with a higher content of light molecules. However, the advantages of using a more complex two steps process still need to be proven.