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- 19th -century environmental transformation of an industrialized estuary: the Avilés sedimentary record (Asturias, N Spain)Publication . Gardoki, Jon; Cearreta, Alejandro; García-Artola, Ane; Irabien, María Jesús; Gomez-Arozamena, Jose; Villasante-Marcos, Víctor; Quijada, I. EmmaABSTRACT: The Avilés estuary is one of the most important industrial ports in northern Spain, whose natural characteristics have been largely altered since the 1830s. Here, the environmental transformation of this estuary during the 19th century is explored using a multi-proxy approach including benthic foraminiferal content, sedimentology (grain-size), trace metals and short-lived radionuclides (210Pb and 137Cs) analysed from a 50-cm-long sediment core and a surface sample collected from the middle part of the estuary in the Pedro Menéndez Channel. The obtained results provide evidence that indicate an evolution from a naturally-driven environment with high a marine influence towards a more restricted setting under brackish conditions. The observed environmental change is interpreted as being mostly derived from physical modifications linked to the marsh reclamation and channelling starting in 1833 and intensified since 1860. This study provides a preindustrial environmental reference framework for future studies in coastal areas of the NW Atlantic Iberian margin.
- 3D Constrained Gravity Inversion and TEM, Seismic Reflection and Drill-Hole Analysis for New Target Generation in the Neves-Corvo VMS Mine Region, Iberian Pyrite BeltPublication . Marques, Fábio; Dias, Pedro; Carvalho, João; Represas, Patricia; Spicer, Bill; Araújo, Vítor; Matos, João Xavier; Morais, Igor; Albardeiro, Luís; Sousa, Pedro; Pacheco, Nelson; Gonçalves, Pedro; Barbosa, DiegoABSTRACT: Located in the Iberian pyrite belt, the Neves-Corvo mine is a world-class massive sulfide deposit and the largest operating mine in Portugal with underground mining down to 1000 m depth focused on massive and stockwork Cu, Zn, Pb rich ores. Gravimetric data have had a leading role in the discovery of the seven known deposits, together with time-domain electromagnetic (TEM) ground data. In this work, we present the results of a 3D constrained gravity inversion carried out with legacy ground gravity data. The 3D gravity inversions were carried out using an updated density database containing approximately 142,000 measurements. A recently constructed 3D geological model based on reprocessed 2D seismic reflection, 3D seismic, TEM and updated geology from detailed surface mapping and drill-hole data, was used to constrain the inversions. The results show multiple high-density anomalies that may indicate the presence of mineralization at depth. These anomalies were therefore cross-checked with holes previously drilled. Approximately 97% of more than 1000 available surface drill-holes located on or at a distance of less than 200 m from the high-density anomalies intersected mineralization. However, gravity anomalies have been drilled in the past and particularly dense black shales or rhyolitic/gabbroic rocks have been intersected. To increase the success of future drilling, gravimetric anomalies have been correlated spatially with high-conductivity TEM zones and strong-amplitude seismic reflections, because igneous rocks usually present weak-to-moderate conductivity and a massive column of black shales presents a seismic signature quite different from that of mineralization. We concluded that some of these locations represent high-quality targets to consider following up with drilling and further exploration.
- 3D electrical structure definition of aquifer systems in the Kalahari basin in Southern Angola based on legacy data reprocessingPublication . Ramalho, Elsa; Francés, Alain Pascal; Santos, Fernando Monteiro; Victorino, Américo da MataABSTRACT: The Kalahari-Ohangwena transboundary aquifer system, recently identified in Northern Namibia, comprises 3 major aquifers with very different characteristics. The shallowest is discontinuous and with limited reserves, but it has local importance in water supply for the population, since it is easy to reach, and often presents good hydrochemical quality. An intermediate deeper aquifer is characterized by high salinity while the deepest aquifer, also mostly saline, can present zones with fresh water. However, the latter is located at considerable depths and is shaped by the bottom of the basin basement. There hasn't been a systematic hydrogeological data acquisition for decades in this area of Angola, but legacy electrical resistivity data reprocessing from geophysical surveys conducted >50 years ago in the Cunene Province allowed the construction of a quasi-3D geoelectrical model for the Angolan side of KOH aquifer system in the Cuvelai-Etosha basin. This model is based on 482 vertical electrical soundings carried out in 1966-67, using the Schlumberger array, that contribute to confirming the presence of the Kalahari-Ohangwena aquifer system in Angola. The obtained quasi-3D model highlights the geoelectrical features of hard bedrock and is validated with other hydrogeological and geophysical information. The quasi-3D electrical resistivity data is interpreted using selected boreholes and two time-domain electro-magnetics transects carried out in Namibia, in the 2000s. Although both geophysical data acquisitions were >40 years apart, the results show a very good correlation between the deeper aquifer and the aquitard separating the intermediate aquifer from the deeper aquifer either with the results from Namibia or the borehole data. This is a direct result of the lack of alteration in the hydraulic conditions over these decades, without significant anthropogenic activity and negligible extraction from deep wells. Based on this analysis, the original dataset was considered a reliable source and this quasi-3D model was validated. Furthermore, the model can be considered in the future as an important tool for groundwater resources management, as well as a good starting point for further hydrogeological research in the province of Cunene.
- 3D reflection seismic imaging of volcanogenic massive sulphides at Neves-Corvo, PortugalPublication . Donoso, George; MALEHMIR, Alireza; Carvalho, João; Araújo, VítorABSTRACT: Three-dimensional reflection seismic data from the Neves-Corvo area, southern Portugal, were reprocessed with the main objective of improving the seismic signature of the Lombador and Semblana volcanogenic massive sulphide deposits. The sensitivity for choosing adequate parameters for targeted imaging, even during the pre-processing stage, such as common-depth point binning size, was studied in detail before the main processing work began helping to optimize bin size parameters; preliminary stacking results from this analysis presented severe acquisition footprint, and seismic targets were not clearly identifiable. Processing results using pre-stack dip move-out and post-stack migration methods show strong moderate to steeply dipping reflections. Several of the observed reflections can be correlated with known lithological contacts, some of which are interpreted to originate from the Semblana and Lombador deposits. Despite the mixed signal-to-noise ratio, the seismic cube reveals both shallow and deep three-dimensional structures, allowing to account for the deposits' lateral extension beyond the capabilities of two-dimensional seismic imaging alone. Given the data processing approach taken it was possible to distinguish strong diffraction patterns, interpreted as originating from faults and edges of the Lombador deposit, illustrating the usefulness of diffraction patterns for better interpretation of geological features in hard-rock environments.
- 87Sr/86Sr dating of the Alcácer do Sal Formation (upper Miocene, mainland Portugal)Publication . Ressurreição, Ricardo; Legoinha, Paulo; Dias, Ruben Pereira; Santos, José Francisco; Ribeiro, Sara; Patinha, Carla; Miranda, RuiThe Lower Tagus Basin was subjected to several marine transgressions along the Neogene, related to positive eustatic oscillations and also controlled by the regional tectonic activity. In the Alcácer do SalSines region, previous studies identified an episode of marine sedimentation interpreted as having occurred during the late Serravalian to early Tortonian interval, based on biostratigraphic data. This episode is represented in the Alcácer do Sal Formation. The study of the SMS-12- 01B borehole, drilled for mineral prospection purposes, located about 10 km NNE of Melides, allowed the identification of a 3 m thick layer of sediments containing marine fossils. 87Sr/86Sr determinations of oyster shells point to deposition about 11.5 Ma ago, validating previous proposals for the age of the formation. These data correspond to the first numerical ages obtained for the Alcácer do Sal Formation, allowing a solid correlation with other known marine units in the Lower Tagus and Algarve basins related to the same transgression episode
- Ability of Gordonia alkanivorans strain 1B for high added value carotenoids productionPublication . Silva, Tiago; Paixão, Susana M.; Alves, LuísCurrently, carotenoids are valuable bioactive molecules for several industries, such as chemical, pharmaceutical, food and cosmetics, due to their multiple benefits as natural colorants, antioxidants and vitamin precursors. Hence, the increasing interest on these high added-value products has led to the search of alternatives, more cost-effective and with better yields, towards their industrial production. Indeed, microbial metabolism offers a promising option for carotenoids production. Herein it is shown the potential of the dibenzothiophene desulfurizing bacterium Gordonia alkanivorans strain 1B as a high carotenoid-producer microorganism. The novel carotenoids, produced under different culture conditions, were extracted with DMSO and then further analyzed both through spectrophotometry and HPLC. When grown in glucose-sulfate-light, strain 1B was able of achieving 2015 g carotenoids per g DCW in shake-flask assays, with about 60% corresponding to lutein, canthaxanthin and astaxanthin. Further optimization studies open a new focus of research aiming to get a hyper pigment-producer strain that may be applied towards different industrial sectors.
- Accelerated aging tests to selective solar absorber coatings for low temperature applicationsPublication . Cunha Diamantino, Teresa; Gonçalves, Rita; Páscoa, Soraia; Alves, Isabel Nascimento; Carvalho, Maria JoãoABSTRACT: The need of a higher role of solar energy within the energy mix in the coming decades obliges the collectors to increase their performance and reliability. It is demanded that the solar absorbers, as the key component of solar thermal collectors, should be low cost with high efficiency for extended lifetimes under different kinds of environments. Commercially, there are presently two main types of solutions as selective solar absorbers coatings for low temperature applications: coatings obtained by physical vapour deposition (PVD) and by paint coatings (PC). These coatings present different physical and chemical characteristics. Therefore, it is important to know how these commercial coatings degrade over time in different environments. Results obtained with two different PVD coatings and three PC, under different accelerated aging tests, are presented. The aging tests performed included different environmental stress corrosion conditions: temperature, humidity, chlorides, sulfur dioxide and nitrogen oxides. The chlorides and the gases SO2 and NO2 affect distinctly the different selective coatings. Cyclic variation of corrosion promoting gases (sulfur dioxide and nitrogen dioxide), higher humidity, salt spraying and drying seem to be an aging test that reflects the different environments where the solar thermal collectors are exposed. In addition to the contaminants, drying/wetting cycles also play an important role in degradation mechanisms of absorber coatings. So, the international standard ISO 22975-3 needs to be revised to include cyclic conditions with these contaminants.
- Acerca da idade das rochas graníticas portuguesasPublication . Teixeira, Carlos
- Acid mine drainage from the Panasqueira mine and its influence on Zêzere river (Central Portugal)Publication . Candeias, Carla; Ávila, Paula Freire; Silva, Eduardo Ferreira da; Ferreira, Adelaide; Salgueiro, Ana Rita; Teixeira, João PauloThe Panasqueira hydrothermal mineralization, located in central Portugal, is the biggest Sn–W deposit of the Western Europe. The main evidences of the mining exploitation and ore treatment operations are testified with huge tailings, mainly, in the Rio and Barroca Grande areas. The mining and beneficiation processes, at the site, produces metal rich mine wastes. Oxidation of sulfides tailings and flow from open impoundments are responsible for the mobilization and migration of metals from the mine wastes into the environment. Acid mine drainage (AMD) discharged from Rio tailing has a pH around 3 and high metal concentrations. In Zêzere river, Fe and As are the most rapidly depleted downstream from AMD once As adsorbs, coprecipitate and form compounds with iron oxyhydroxides. The Zêzere river waters are oversaturated with respect to kaolinite and goethite and ferrihydrite can precipitate on stream with a near-neutral pH. At sites having low pH the dissolved Fe species in the water, mainly, occur as sulfate complexes due to a high SO4 concentration. Melanterite (Fe2+(SO4)·7(H2O)) and minor amounts of rozenite (Fe2+(SO4)·4(H2O)) and szomolnokite (Fe2+(SO4)·(H2O)) were observed on Rio tailing basement.
- Acid-modified clays as green catalysts for the hydrolysis of hemicellulosic oligosaccharidesPublication . Vilcocq, Léa; Spinola, Vitor; Moniz, Patricia; Duarte, Luís C.; Carvalheiro, Florbela; Fernandes, César; Castilho, Paula C.The hydrolysis of hemicellulosic oligosaccharides (OS) was investigated using acid-activated clays (prepared from natural Porto Santo montmorillonite clay) as catalysts. Acid activation was performed in HCl solution or with aluminium exchange. The clay catalysts were characterized by XRD, N2 adsorption isotherms, CEC, FTIR, titration of acid sites in water and adsorption of sugars and disaccharides. They were tested for the hydrolysis of a model compound, maltose, and of OS-rich liquor from rice straw fractionation. The HCl-activated clays were the most efficient catalysts for maltose hydrolysis. It was demonstrated that the hydrolysis of OS into monomer sugars over a clay catalyst is technically feasible and that this reaction leads to the selective removal of glucose, arabinose and acetic acid side groups from the OS structure, thus yielding simpler xylo-oligosaccharide chains. Furthermore, no significant conversion of monomer sugars into furans was observed.