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Ultrafast low-temperature crystallization of solar cell graded formamidinium-cesium mixed-cation lead mixed-halide perovskites using a reproducible microwave-based process

Publication . Brites, Maria João; Barreiros, M. Alexandra; Corregidor, V.; Alves, L. C.; Pinto, Joana V.; Mendes, Manuel Joao; Fortunato, Elvira; Martins, Rodrigo; Mascarenhas, João

ABSTRACT: The control of morphology and crystallinity of solution-processed perovskite thin-films for solar cells is the key for further enhancement of the devices’ power conversion efficiency and stability. Improving crystallinity and increasing grain size of perovskite films is a proven way to boost the devices’ performance and operational robustness, nevertheless this has only been achieved with high-temperature processes. Here, we present an unprecedented low-temperature (<80 °C) and ultrafast microwave (MW) annealing process to yield uniform, compact, and crystalline FA0.83Cs0.17Pb(I(1–x)Brx)3 perovskite films with full coverage and micrometer-scale grains. We demonstrate that the nominal composition FA0.83Cs0.17PbI1.8Br1.2 perovskite films annealed at 100 W MW power present the same band gap, similar morphology, and crystallinity of conventionally annealed films, with the advantage of being produced at a lower temperature (below 80 °C vs 185 °C) and during a very short period of time (∼2.5 min versus 60 min). These results open new avenues to fabricate band gap tunable perovskite films at low temperatures, which is of utmost importance for Mechanically flexible perovskite cells and monolithic perovskite based tandem cells applications.

2019Journal article

Open access

Análogos geoquímicos portugueses de rochas e solos marcianos (S. Saturnino – Fronteira vs Cratera de Gusev e Meridiani Planum)

Publication . Rocha, Carla; Alves, Eduardo Ivo

RESUMO: Este trabalho resulta de estudos petrográficos e geoquímicos feitos sobre afloramentos de rochas filonianas básicas na região de S. Saturnino (Fronteira, Portalegre, Portugal) como análogos de rochas e solos marcianos das regiões da cratera Gusev e de Meridiani Planum analisados nas missões dos rovers Spirit (MER-A) e Opportunity (MER-B). Mostra-se que este é o primeiro local em Portugal Continental que pode ser reconhecido como análogo dos ambientes geológico, petrográfico e geoquímico marcianos.

2025-04Journal article

Open access