Publication
Manufacture of furfural in biphasic media made up of an ionic liquid and a co-solvent
| dc.contributor.author | Peleteiro, Susana | |
| dc.contributor.author | Lopes, André | |
| dc.contributor.author | Garrote, Gil | |
| dc.contributor.author | Lukasik, Rafal M. | |
| dc.contributor.author | Parajó, J. C. | |
| dc.date.accessioned | 2016-03-14T13:18:35Z | |
| dc.date.available | 2016-03-14T13:18:35Z | |
| dc.date.issued | 2015 | |
| dc.description.abstract | Xylose was converted into furfural operating in a medium containing the acidic ionic liquid (AIL) 1-butyl-3-methylimidazolium hydrogen sulfate, in the presence of toluene as a co-solvent. No catalytic species different from the AIL were needed for furfural production from xylose. Operating at 100.140 .C for 15.480 min in media containing 10 g xylose/100 g AIL and 2.4 g toluene/g (AIL + xylose), most furfural generated in the AIL phase was transferred to the co-solvent, limiting the losses caused by undesired side reactions. Operating under optimal conditions (140 .C for 240 min using 4.4 g toluene/g initial AIL phase), xylose was almost completely consumed, and furfural was obtained at 73.8% of the stoichiometric yield. | pt_PT |
| dc.identifier.citation | Peleteiro, S.; Lopes, A.M. da Costa; Garrote, G.; Bogel-Lukasik, R.; Parajó, J.C. - Manufacture of furfural in biphasic media made up of an ionic liquid and a co-solvent. In: Industrial Crops and Products, 2015, Vol. 77, p. 163-166 | pt_PT |
| dc.identifier.doi | 10.1016/j.indcrop.2015.08.048 | pt_PT |
| dc.identifier.issn | 0926-6690 | |
| dc.identifier.uri | http://hdl.handle.net/10400.9/2880 | |
| dc.language.iso | eng | pt_PT |
| dc.peerreviewed | yes | pt_PT |
| dc.publisher | Elsevier | pt_PT |
| dc.relation.publisherversion | http://dx.doi.org/10.1016/j.indcrop.2015.08.048 | pt_PT |
| dc.subject | Ionic liquids | pt_PT |
| dc.subject | Biphasic systems | pt_PT |
| dc.subject | Sulfate | pt_PT |
| dc.subject | Toluene | pt_PT |
| dc.subject | Furfural production | pt_PT |
| dc.subject | Xylose | pt_PT |
| dc.title | Manufacture of furfural in biphasic media made up of an ionic liquid and a co-solvent | pt_PT |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| oaire.citation.endPage | 166 | pt_PT |
| oaire.citation.startPage | 163 | pt_PT |
| oaire.citation.title | Industrial Crops and Products | pt_PT |
| oaire.citation.volume | 77 | pt_PT |
| person.familyName | Lukasik | |
| person.givenName | Rafal | |
| person.identifier.orcid | 0000-0002-7805-5744 | |
| person.identifier.rid | A-6315-2011 | |
| person.identifier.scopus-author-id | 6506737268 | |
| rcaap.rights | openAccess | pt_PT |
| rcaap.type | article | pt_PT |
| relation.isAuthorOfPublication | 6a7fdbd9-7961-407e-88d0-15d175ea711d | |
| relation.isAuthorOfPublication.latestForDiscovery | 6a7fdbd9-7961-407e-88d0-15d175ea711d |