Publication
CO2+Methanol+Glycerol : multiphase behaviour
| dc.contributor.author | Carrera, Gonçalo V. S. M. | |
| dc.contributor.author | Visak, Zoran P. | |
| dc.contributor.author | Lukasik, Rafal M. | |
| dc.contributor.author | Ponte, Manuel Nunes | |
| dc.date.accessioned | 2019-02-01T15:09:45Z | |
| dc.date.available | 2019-02-01T15:09:45Z | |
| dc.date.issued | 2018 | |
| dc.description.abstract | ABSTRACT: The phase behaviour of the system CO2+methanol+glycerol has been studied at low concentrations of this trialcohol. The synthetic method was implemented in a visual sapphire cell. New phase diagrams were obtained at temperatures of 313.15 and 333.15 K. Different methanol/glycerol molar ratios of 113, 50 and 30 were considered and its influence on phase behaviour accounted for. Pressures were varied from 6.03 to 11.44 MPa. A specific experiment is reported, starting from an initial volume of 4 mL of liquid mixture methanol+glycerol (methanol/glycerol molar ratio 30), where, with a stepwise addition of CO2, diverse fluid phase phenomena were detected, such as VLE, Critical Point, VLLE, VLLLE, LLE and LE. | pt_PT |
| dc.description.version | info:eu-repo/semantics/publishedVersion | pt_PT |
| dc.identifier.citation | Carrera, Gonçalo V.S.M... [et.al.] - CO2+Methanol+Glycerol : multiphase behaviour. In: The Journal of Supercritical Fluids, 2018, Vol. 141, p. 260-264 | pt_PT |
| dc.identifier.issn | 0896-8446 | |
| dc.identifier.uri | http://hdl.handle.net/10400.9/3123 | |
| dc.language.iso | eng | pt_PT |
| dc.peerreviewed | yes | pt_PT |
| dc.publisher | Elsevier | pt_PT |
| dc.relation | PTDC/ EQU-EPR/103505/2008 | pt_PT |
| dc.relation.publisherversion | https://doi.org/10.1016/j.supflu.2017.12.032 | pt_PT |
| dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | pt_PT |
| dc.subject | Supercritical carbon dioxide | pt_PT |
| dc.subject | Glycerol | pt_PT |
| dc.subject | Liquid-liquid equilibrium | pt_PT |
| dc.title | CO2+Methanol+Glycerol : multiphase behaviour | pt_PT |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| oaire.awardURI | info:eu-repo/grantAgreement/FCT/COMPETE/PEst-C%2FEQB%2FLA0006%2F2013/PT | |
| oaire.awardURI | info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F72095%2F2010/PT | |
| oaire.citation.endPage | 264 | pt_PT |
| oaire.citation.startPage | 260 | pt_PT |
| oaire.citation.title | The Journal of Supercritical Fluids | pt_PT |
| oaire.citation.volume | 141 | pt_PT |
| oaire.fundingStream | COMPETE | |
| oaire.fundingStream | SFRH | |
| person.familyName | Lukasik | |
| person.givenName | Rafal | |
| person.identifier.orcid | 0000-0002-7805-5744 | |
| person.identifier.rid | A-6315-2011 | |
| person.identifier.scopus-author-id | 6506737268 | |
| project.funder.identifier | http://doi.org/10.13039/501100001871 | |
| project.funder.identifier | http://doi.org/10.13039/501100001871 | |
| project.funder.name | Fundação para a Ciência e a Tecnologia | |
| project.funder.name | Fundação para a Ciência e a Tecnologia | |
| rcaap.rights | openAccess | pt_PT |
| rcaap.type | article | pt_PT |
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