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Comparison of the corrosion of ferritic and austenitic stainless steel (AISI 430 and AISI 316L) with LiNaK carbonate salts for thermal energy storage in CSP/CST applications

datacite.subject.fosEngenharia e Tecnologia::Engenharia dos Materiais
datacite.subject.sdg09:Indústria, Inovação e Infraestruturas
datacite.subject.sdg12:Produção e Consumo Sustentáveis
dc.contributor.authorGil, Mafalda
dc.contributor.authorPedrosa, Fátima
dc.contributor.authorPaiva Luís, Teresa
dc.contributor.authorFigueira Vasques, Isabel
dc.contributor.authorOliveira, Fernando
dc.contributor.authorCunha Diamantino, Teresa
dc.date.accessioned2025-09-03T13:49:44Z
dc.date.available2025-09-03T13:49:44Z
dc.date.issued2025-07
dc.description.abstractABSTRACT: This study focuses on the corrosion rates and mechanisms of two stainless steels, austenitic AISI 316L and ferritic AISI 430, in contact with a eutectic mixture of LiNaK carbonates in long-term tests at 650 degrees C. The selection of these two stainless steels was based on their differences, both in their intrinsic characteristics and in the cost associated with each one. The research also underscores the importance of optimizing the descaling methods used to evaluate the corrosion rate. Corrosion rates were measured gravimetrically according to ISO 17245:2015, revealing an asymptotic behavior for both steels, with AISI 430 with a corrosion rate of 237 f 21 mu m and AISI 316L of 151 f 13 mu m after 2000 h of testing. Corrosion mechanisms were analyzed using SEM/EDS, GDOES, and XRD techniques, which identified well-defined oxide layers with varying compositions. Given the observed corrosion mechanisms and its lower cost, AISI 430 steel seems to have great applicability in CSP/CST plants, provided it is paired with an appropriate protective coating.eng
dc.identifier.citationGil, M., Paiva, T., Figueira, I., Oliveira, F.A.C. & Diamantino, T.C. (2025). Comparison of the corrosion of ferritic and austenitic stainless steel (AISI 430 and AISI 316L) with LiNaK carbonate salts for thermal energy storage in CSP/CST applications. In: Solar Energy, 2025, vol. 298, article 113743. https://doi.org/10.1016/j.solener.2025.113743
dc.identifier.doi10.1016/j.solener.2025.113743
dc.identifier.eissn1471-1257
dc.identifier.issn0038-092X
dc.identifier.urihttp://hdl.handle.net/10400.9/6027
dc.language.isoeng
dc.peerreviewedyes
dc.publisherElsevier
dc.relationNew materials approaches for concentrating solar power (CSP): Molten salts and Corrosion Protection.
dc.relation.hasversionhttps://www.sciencedirect.com/science/article/pii/S0038092X25005067?via%3Dihub
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectCorrosion
dc.subjectThermal energy storage
dc.subjectMolten salt
dc.subjectStainless steels
dc.subjectConcentrated solar thermal
dc.titleComparison of the corrosion of ferritic and austenitic stainless steel (AISI 430 and AISI 316L) with LiNaK carbonate salts for thermal energy storage in CSP/CST applicationseng
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleNew materials approaches for concentrating solar power (CSP): Molten salts and Corrosion Protection.
oaire.awardURIhttp://hdl.handle.net/10400.9/5587
oaire.citation.titleSolar Energy
oaire.citation.volume298
oaire.fundingStream3599-PPCDT
oaire.versionhttp://purl.org/coar/version/c_970fb48d4fbd8a85
person.familyNameGil
person.familyNamePedrosa
person.familyNamePaiva Luís
person.familyNameFigueira Vasques
person.familyNameOliveira
person.familyNameCunha Diamantino
person.givenNameMafalda
person.givenNameFátima
person.givenNameTeresa
person.givenNameIsabel
person.givenNameFernando
person.givenNameTeresa
person.identifier647144
person.identifier.ciencia-idCB19-84E9-6780
person.identifier.ciencia-id561B-597F-9D55
person.identifier.ciencia-idA81C-1FE7-1D42
person.identifier.orcid0000-0003-1962-0894
person.identifier.orcid0000-0002-0479-822X
person.identifier.orcid0000-0002-3000-5246
person.identifier.orcid0000-0002-0977-7786
person.identifier.orcid0000-0002-1503-0152
person.identifier.orcid0000-0002-0481-0460
person.identifier.ridA-2312-2011
person.identifier.ridG-5063-2017
person.identifier.scopus-author-id23019925500
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