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Cr(III) dynamic removal in a fixed-bed column by using a co-gasification char

dc.contributor.authorDias, Diogo
dc.contributor.authorBernardo, Maria
dc.contributor.authorPinto, Filomena
dc.contributor.authorFonseca, Isabel Maria
dc.contributor.authorLapa, Nuno
dc.date.accessioned2021-11-18T17:05:03Z
dc.date.available2021-11-18T17:05:03Z
dc.date.issued2021-10
dc.description.abstractABSTRACT: A char (GC) obtained from the co-gasification of rice husk and polyethylene was used in a fixed-bed column with continuous flow for Cr(III) removal assays from synthetic and industrial wastewaters. For comparison purposes, a commercial activated carbon (CAC) was also used. The best experimental conditions in the continuous removal assays were the following ones: Cr(III) inflow concentration = 5 mg L-1, feed flow rate = 3 mL min(-1), mass of adsorbent in the column = 0.8 g, and inflow temperature = 50 degrees C. Under these conditions, the highest uptake capacities were 1.60 and 2.14 mg g(-1) in the synthetic solution, and 3.25 and 7.83 mg g(-1) in the industrial wastewater, for GC and CAC, respectively. These results are different from those obtained under batch conditions in which GC performed better than CAC. Cr(III) removal by both adsorbents occurred due to precipitation, but CAC presented a slightly higher amount of Cr(III) removed due to its highest porosity. The regeneration of GC and CAC was also studied, but both adsorbents showed no capacity to be used in more than one cycle. This study highlighted the importance of studying Cr(III) removal under continuous conditions, as the removal mechanisms may be completely different from the batch assays, affecting the adsorbents' performance.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationDias, D... [et.al.] - Cr(III) dynamic removal in a fixed-bed column by using a co-gasification char. In: International Journal of Environmental Science and Technology, 2021 [Early Access]pt_PT
dc.identifier.doi10.1007/s13762-021-03690-8pt_PT
dc.identifier.eissn1735-2630
dc.identifier.issn1735-1472
dc.identifier.urihttp://hdl.handle.net/10400.9/3608
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherSpringerpt_PT
dc.relationFCOMP-01-0124-FEDER-027827pt_PT
dc.relationAssociated Laboratory for Green Chemistry - Clean Technologies and Processes
dc.relationRecuperação de metais com elevado valor comercial através da adsorção por carbonizados provenientes de resíduos da cultura do arroz Rice2Metal
dc.relation.publisherversionhttps://doi.org/10.1007/s13762-021-03690-8pt_PT
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt_PT
dc.subjectRice wastespt_PT
dc.subjectWastewaterpt_PT
dc.subjectCo-gasificationpt_PT
dc.subjectChromiumpt_PT
dc.subjectAdsorptionpt_PT
dc.subjectActivated carbonspt_PT
dc.subjectIndustrial wastewaterspt_PT
dc.titleCr(III) dynamic removal in a fixed-bed column by using a co-gasification charpt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleAssociated Laboratory for Green Chemistry - Clean Technologies and Processes
oaire.awardTitleRecuperação de metais com elevado valor comercial através da adsorção por carbonizados provenientes de resíduos da cultura do arroz Rice2Metal
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/COMPETE/PTDC%2FAAG-REC%2F3477%2F2012/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/5876-PPCDTI/PTDC%2FAAG-REC%2F3477%2F2012/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F50006%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/OE/SFRH%2FBD%2F101751%2F2014/PT
oaire.citation.titleInternational Journal of Environmental Science and Technologypt_PT
oaire.fundingStreamCOMPETE
oaire.fundingStream5876-PPCDTI
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStreamOE
person.familyNameDias
person.familyNameBernardo
person.familyNamePinto
person.familyNameLapa
person.givenNameDiogo
person.givenNameMaria
person.givenNameFilomena
person.givenNameNuno
person.identifier90528
person.identifier.ciencia-id1E11-A847-44DA
person.identifier.ciencia-id5A14-EADB-672D
person.identifier.orcid0000-0002-9757-1605
person.identifier.orcid0000-0002-5823-6636
person.identifier.orcid0000-0002-1014-568X
person.identifier.orcid0000-0001-7862-7477
person.identifier.ridC-4035-2015
person.identifier.ridB-5187-2015
person.identifier.ridK-8456-2013
person.identifier.scopus-author-id55385919600
person.identifier.scopus-author-id22933828300
person.identifier.scopus-author-id7102740188
person.identifier.scopus-author-id6602694802
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
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