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Scale-up of a system for hydrocarbon production by electrochemical reduction of CO2

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This work addresses the scaling up of a system for electrochemical reduction of CO2 to produce hydrocarbons that can be used as fuel for a regenerative energy storage cycle. Challenges involved in such a task are mentioned. Scalingup results of a system based on electrodes of high surface area with modified copper deposits are described. Current densities around 100 mA/cm2 were obtained. This corresponds to the current density threshold that enables technological applications. At potentials as negative as -1.6 V it was observed that CO2 reduction still dominated over hydrogen evolution reaction.

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Fernandes, T. R. C.; Machado, A. S. Reis; Rangel, C. M.; Condeço, J.; Pardal, T. Scale-up of a system for hydrocarbon production by electrochemical reduction of CO2. In: Fuel Cells, 9th European Space Power Conference : session 9. St. Rafael, France, June 2011

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