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Techno-economic and life-cycle assessments of small-scale biorefineries for isobutene and xylo-oligosaccharides production: a comparative study in Portugal and Chile

dc.contributor.authorLopes, Tiago
dc.contributor.authorCarvalheiro, Florbela
dc.contributor.authorDuarte, Luís C.
dc.contributor.authorGírio, Francisco
dc.contributor.authorQuintero, Julián A.
dc.contributor.authorAroca, Germán
dc.date.accessioned2020-05-28T15:01:05Z
dc.date.available2020-05-28T15:01:05Z
dc.date.issued2019
dc.description.abstractABSTRACT: This work presents a comparative simulation study involving the techno-economic and environmental assessment of lignocellulosic-based small-scale biorefineries, integrated with a piggery waste-based anaerobic digestion platform (ADB), located in Portugal and Chile. Two main products are obtained: isobutene and xylo-oligosaccharides (XOS). The bioproduction of isobutene using a genetically engineered organism (Escherichia coli), coupled with the removal and purification of high added-value XOS, obtained after a feedstock hydrothermal pre-treatment, was evaluated. Two lignocellulosic agricultural wastes were used: corn stover in the Portuguese case study and wheat straw in Chilean case study. Both processes were simulated using the Aspen Plus modeling software tool, while the Aspen Process Economic Analyzer was used to carry out the economic evaluation. The simulation results were validated with experimental data from the laboratory and the literature. An economic assessment was performed considering the different locations of both biorefineries. A life-cycle analysis (LCA) was also applied to evaluate the differences in environmental impacts on both locations. The results showed that the isobutene / XOS biorefinery concept was economically viable in both Portugal and Chile, mainly due to the high market value of XOS. The biorefinery has lower production costs for isobutene and XOS (1 US$/kg of isobutene and 1.18 US$/kg of XOS) when located in Portugal, as compared with Chile (1.14 US$/kg of isobutene and 1.56 US$/kg of XOS). Conversely, it leads to less environmental impact when located in Chile: 48.8 kg(CO2eq.)/GJ(isobutene), in comparison to 60.7 kg(CO2eq.)/GJ(isobutene) in Portugal.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationLopes, Tiago F... [et.al.] - Techno-economic and life-cycle assessments of small-scale biorefineries for isobutene and xylo-oligosaccharides production: a comparative study in Portugal and Chile. In: Biofuels Bioproducts & Biorefining, 2019, Vol. 13(5), p. 1321-1332pt_PT
dc.identifier.doi10.1002/bbb.2036pt_PT
dc.identifier.issn1932-104X
dc.identifier.urihttp://hdl.handle.net/10400.9/3276
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherJohn Wiley and Sonspt_PT
dc.relationSMIBIO project (ELAC2014/ BEE-0249)pt_PT
dc.relation.publisherversionhttps://doi.org/10.1002/bbb.2036pt_PT
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt_PT
dc.subjectBiorefinerypt_PT
dc.subjectBiofuelspt_PT
dc.subjectLCApt_PT
dc.subjectAutohydrolysispt_PT
dc.subjectResiduespt_PT
dc.titleTechno-economic and life-cycle assessments of small-scale biorefineries for isobutene and xylo-oligosaccharides production: a comparative study in Portugal and Chilept_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage1332pt_PT
oaire.citation.startPage1321pt_PT
oaire.citation.titleBiofuels, Bioproducts and Biorefiningpt_PT
oaire.citation.volume13pt_PT
person.familyNameLopes
person.familyNameCarvalheiro
person.familyNameDuarte
person.familyNameFERREIRA GIRIO
person.givenNameTiago
person.givenNameFlorbela
person.givenNameLuís
person.givenNameFRANCISCO MANUEL
person.identifier59799
person.identifier.ciencia-id4016-9476-B97D
person.identifier.ciencia-id7F15-9BC9-79AA
person.identifier.ciencia-idD51D-09A4-A2DC
person.identifier.orcid0000-0002-9720-8777
person.identifier.orcid0000-0002-0270-4832
person.identifier.orcid0000-0001-5820-3669
person.identifier.orcid0000-0002-5376-8430
person.identifier.ridL-1860-2014
person.identifier.ridC-1430-2008
person.identifier.scopus-author-id6603247136
person.identifier.scopus-author-id56649966600
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
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relation.isAuthorOfPublication.latestForDiscovery844a40eb-c914-4b16-9888-d58f7beb22e0

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