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Experimental and modeling studies of a micro direct methanol fuel cell

dc.contributor.authorFalcão, D. S.
dc.contributor.authorOliveira, V. B.
dc.contributor.authorRangel, C. M.
dc.contributor.authorPinto, A. M. F. R.
dc.date.accessioned2016-04-26T15:43:27Z
dc.date.available2016-04-26T15:43:27Z
dc.date.issued2015
dc.description.abstractThe Direct Methanol Fuel Cell (DMFC) has attracted much attention due to its potential applications as a power source for transportation and portable electronic devices. Based on the advantages of the scaling laws, miniaturization promises higher efficiency and performance of power generating devices and the MicroDMFC is therefore an emergent technology. In this work, a set of experiments with a MicroDMFC of 2.25 cm2 active area are performed in order to investigate the effect of important operating parameters. Maximum power density achieved was 32 mW/cm2 using a 4 M methanol concentration at room temperature. Polarization curves are compared with mathematical model simulations in order to achieve a better understanding of how parameters affect performance. The one-dimensional model used in this work takes in account coupled heat and mass transfer, along with the electrochemical reactions occurring in a direct methanol fuel cell and was already developed and validated for DMFC in previous work by Oliveira et al. [1–3]. The model is also used to predict some important parameters to analyze fuel cell performance, such as water transport coefficient and methanol crossover. This easy to implement simplified model is suitable for use in real-time MicroDMFC simulations. More experimental data are also reported bearing in mind the insufficient experimental data available in literature at room temperature, a goal condition to use this technology in portable applications.pt_PT
dc.identifier.citationFalcão, D.S.; Oliveira, V.B.; Rangel, C.M.; Pinto, A.M.F.R. - Experimental and modeling studies of a micro direct methanol fuel cell. In: Renewable Energy, 2015, Vol. 74, p. 464-470pt_PT
dc.identifier.doi10.1016/j.renene.2014.08.043pt_PT
dc.identifier.issn0960-1481
dc.identifier.urihttp://hdl.handle.net/10400.9/2949
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherElsevierpt_PT
dc.relationMICROFCELLS - Miniaturization Direct Methanol Fuel Cells: design, modelling and optimization
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.renene.2014.08.043pt_PT
dc.subjectMicroDMFCpt_PT
dc.subjectExperimental Studiespt_PT
dc.subjectModellingpt_PT
dc.subjectHeat and mass transferpt_PT
dc.subjectFuel cellspt_PT
dc.subjectFuel cell performancept_PT
dc.titleExperimental and modeling studies of a micro direct methanol fuel cellpt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleMICROFCELLS - Miniaturization Direct Methanol Fuel Cells: design, modelling and optimization
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/5876-PPCDTI/PTDC%2FEQU-FTT%2F112475%2F2009/PT
oaire.citation.endPage470pt_PT
oaire.citation.startPage464pt_PT
oaire.citation.titleRenewable Energypt_PT
oaire.citation.volume74pt_PT
oaire.fundingStream5876-PPCDTI
person.familyNameRangel
person.givenNameCarmen M.
person.identifier.ciencia-idAA13-FF7C-9E29
person.identifier.orcid0000-0001-7996-8142
person.identifier.ridD-5477-2011
person.identifier.scopus-author-id7006108156
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublication804e595a-d539-46a2-ae78-6cadc8ca9457
relation.isAuthorOfPublication.latestForDiscovery804e595a-d539-46a2-ae78-6cadc8ca9457
relation.isProjectOfPublicationfa630004-2c44-42d3-b813-2803452cd45c
relation.isProjectOfPublication.latestForDiscoveryfa630004-2c44-42d3-b813-2803452cd45c

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