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Simple and efficient furfural production from xylose in media containing 1-Butyl-3-Methylimidazolium hydrogen sulfate
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Orientador(es)
Resumo(s)
The acidic 1-butyl-3-methylimidazolium hydrogen sulfate ([bmim][HSO4]) ionic liquid was explored as both a reaction medium and a catalyst in the furfural production from xylose. Preliminary experiments were carried out at 100–140 °C for 15–480 min in systems containing just xylose dissolved in [bmim][HSO4] in the absence of externally added catalysts. More than 95% xylose conversion was achieved when operating at 120 or 140 °C for 300 and 90 min, respectively; but just 36.7% of the initial xylose was converted to furfural. Operation in biphasic reaction systems (in the presence of toluene, methyl-isobutyl ketone or dioxane as extraction solvents) at 140 °C under selected conditions resulted in improved furfural production (73.8%, 80.3%, and 82.2% xylose conversion to furfural for the cited extraction solvents, respectively).
Descrição
Palavras-chave
Ionic liquids Sulfate Furfural production Xylose
Contexto Educativo
Citação
Peleteiro, S.; Lopes, A.M. da Costa; Garrote, G.; Parajó, J.C.; Bogel-Lukasik, R. - Simple and efficient furfural production from xylose in media containing 1-Butyl-3-Methylimidazolium hydrogen sulfate. In: Industrial and Engineering Chemistry Research, 2015, Vol. 54, nº 33, p. 8368–8373
Editora
ACS Publications - American Chemical Society