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Kinetic modeling of self-hydrolysis of aqueous NaBH4 solutions by model-based isoconversional method 

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dc.contributor.authorRetnamma, Rajasree
dc.contributor.authorNovais, Augusto Q.
dc.contributor.authorRangel, C. M.
dc.contributor.authorYu, Lin
dc.contributor.authorMatthews, Michael A.
dc.date.accessioned2015-03-11T16:42:27Z
dc.date.available2015-03-11T16:42:27Z
dc.date.issued2014
dc.description.abstractThe present work reports the kinetic modeling of self-hydrolysis of non-buffered, nonstabilized NaBH4 solutions by model-based isoconversional method. The overall kinetics is described by a ‘reaction-order’ model in a practical operating window of 10-20 wt% NaBH4 solutions at 25-80 ºC and 0-50% conversions. The apparent activation energy and preexponential factor are interrelated through a kinetic compensation effect (KCE). The apparent reaction order remains constant at a given temperature irrespective of extent of conversion and decreases with increase in temperature. It decreases from first-order to 0.26 with increase in temperature from 25 to 80 ºC. por
dc.identifier.citationRetnamma, R.; Novais, A.Q.; Rangel, C.M.; Yu, L.; Matthews, M.A. - Kinetic modeling of self-hydrolysis of aqueous NaBH4 solutions by model-based isoconversional method. In: International Journal of Hydrogen Energy, 2014, Vol. 39, p. 6567-6576por
dc.identifier.issn0360-3199
dc.identifier.urihttp://hdl.handle.net/10400.9/2632
dc.language.isoengpor
dc.publisherElsevierpor
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.ijhydene.2014.02.035por
dc.subjectHydrogen productionpor
dc.subjectIsoconversional methodpor
dc.subjectKineticspor
dc.subjectSelf-hydrolysispor
dc.subjectSodium borohydridepor
dc.titleKinetic modeling of self-hydrolysis of aqueous NaBH4 solutions by model-based isoconversional method por
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage6576por
oaire.citation.startPage6567por
oaire.citation.titleInternational Journal of Hydrogen Energypor
oaire.citation.volume39por
person.familyNameRangel
person.givenNameCarmen M.
person.identifier.ciencia-idAA13-FF7C-9E29
person.identifier.orcid0000-0001-7996-8142
person.identifier.ridD-5477-2011
person.identifier.scopus-author-id7006108156
rcaap.rightsopenAccesspor
rcaap.typearticlepor
relation.isAuthorOfPublication804e595a-d539-46a2-ae78-6cadc8ca9457
relation.isAuthorOfPublication.latestForDiscovery804e595a-d539-46a2-ae78-6cadc8ca9457

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