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Co-pyrolysis of wastes mixtures obtained from rice production: upgrading of produced liquids

dc.contributor.authorPinto, Filomena
dc.contributor.authorMiranda, Miguel
dc.contributor.authorCosta, Paula
dc.date.accessioned2016-04-12T16:14:54Z
dc.date.available2016-04-12T16:14:54Z
dc.date.issued2015
dc.description.abstractThe increasing need to find alternative fuels to decrease the dependency on fossil fuels and to reduce the negative environmental impact of wastes accumulation has led to the idea of studying the energetic valorisation of different types of wastes by co-pyrolysis. Rice production process generates rice husk together with polyethylene (PE) bags that are used for rice packaging and to transport seeds and fertilizers used for rice culture. In Portugal, most of these plastic bags waste usually end up in landfills, since the amount of dirt and dust does not allow their recycling. Bio-oils produced by rice wastes pyrolysis present some undesirable properties: chemical instability, high solids content, ashes, oxygenated compounds and water, which prevent its direct use in conventional engines. On the other hand, PE pyrolysis produces around 80% w/w of liquid hydrocarbons (bio-oils) composed by a complex mixture of hydrocarbons from C5 to C20 (without the mentioned undesirable properties), 10% w/w of gases and almost no solids. Co-pyrolysis of rice husk blended with plastic wastes leads to the production of bio-oils that may be used as bio-fuels or as raw materials. These bio-oils quality can be improved by the optimisation of co-pyrolysis experimental conditions, including the use of suitable catalysts. Otherwise, liquids may be thermally upgraded to convert heavier liquid molecules into smaller ones with lower molecular weight and better fuel properties. The capability of these bio-fuels for energy production to be used during rice milling processes was analysed. Different approaches: pyrolysis, hydrogenation and pyrolysis followed by hydrogenation were analysed, considering the technical, economical and environmental viability of each process.pt_PT
dc.identifier.citationPinto, F.; Miranda, M.; Costa, P. - Co-pyrolysis of wastes mixtures obtained from rice production: upgrading of produced liquids. In: Chemical Engineering Transactions, 2015, Vol. 43, p. 2053-2058pt_PT
dc.identifier.doi10.3303/CET1543343pt_PT
dc.identifier.issn2283-9216
dc.identifier.urihttp://hdl.handle.net/10400.9/2932
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherAIDIC - The Italian Association of Chemical Engineeringpt_PT
dc.relation.publisherversionhttp://dx.doi.org/10.3303/CET1543343pt_PT
dc.subjectCo-pyrolysispt_PT
dc.subjectWaste valorizationpt_PT
dc.subjectRice wastespt_PT
dc.subjectEnergetic valorisationpt_PT
dc.titleCo-pyrolysis of wastes mixtures obtained from rice production: upgrading of produced liquidspt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/5876-PPCDTI/PTDC%2FAAG-REC%2F3477%2F2012/PT
oaire.citation.endPage2058pt_PT
oaire.citation.startPage2053pt_PT
oaire.citation.titleChemical Engineering Transactionspt_PT
oaire.citation.volume43pt_PT
oaire.fundingStream5876-PPCDTI
person.familyNamePinto
person.familyNameMiranda
person.familyNameCosta
person.givenNameFilomena
person.givenNameMiguel
person.givenNamePaula
person.identifier.ciencia-id4C1B-3AF1-8A48
person.identifier.ciencia-id2A1B-0AB6-B0FB
person.identifier.orcid0000-0002-1014-568X
person.identifier.orcid0000-0001-9318-1506
person.identifier.orcid0000-0003-2024-4267
person.identifier.ridD-9167-2013
person.identifier.ridP-6395-2015
person.identifier.scopus-author-id7102740188
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublication115c7b3c-916f-448e-b2d3-c2f3a186d1a2
relation.isAuthorOfPublication84d6b748-8faf-4cd7-bdde-e039d63c568f
relation.isAuthorOfPublication1c496336-8d21-4ed3-8d57-ade6c4a4ae1f
relation.isAuthorOfPublication.latestForDiscovery115c7b3c-916f-448e-b2d3-c2f3a186d1a2
relation.isProjectOfPublication6fc0ebb2-16cd-47eb-afd3-5bfc70db4a66
relation.isProjectOfPublication.latestForDiscovery6fc0ebb2-16cd-47eb-afd3-5bfc70db4a66

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