Chemical Activities, a(H) and a(X), of Constituents in H2X Type Gas Molecules (X = O or S) at Arbitrary Degree of Dissociation

Shohoji, Nobumitsu

http://hdl.handle.net/10400.9/1686

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Authors

Shohoji, Nobumitsu

Abstract(s)

Chemical activities, a(X) and a(H), of constituents, X and H, in H2X type gas molecules (X = S or O) were evaluated as functions of temperature T and extent α of dissociation adapting a thermodynamic analysis procedure developed by Katsura for interpreting enhanced a(N) and a(H) in NH3 gas molecules with suppressed α by flowing. Present analysis results showed that both H2S and H2O gas molecules are chemically rather inert even at comparatively low α unlike nitrogen-family tri-hydrides XH3 that were proved to yield high chemical activity of each constituent in a state being away from thermodynamic equilibrium. The parameter α referring to the extent of dissociation of HnX type gas molecules appears to be a significant parameter in evaluating the chemical activities, a(X) and a(H), in the HnX gas molecules that are remained non-dissociated.

Keywords

Thermodynamics Chemical activity Dissociation Non-equilibrium state H2S H2O

URI

http://hdl.handle.net/10400.9/1686

Citation

Shohoji, N. Chemical Activities, a(H) and a(X), of Constituents in H2X Type Gas Molecules (X = O or S) at Arbitrary Degree of Dissociation. In: International Journal of Materials and Chemistry, 2012, vol. 2, nº 1, p. 10-15