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Leaching behavior of several zinc rich residues in a hydrometallurgical recycling process

dc.contributor.authorPedrosa, Fátima
dc.contributor.authorCabral, Marta
dc.contributor.authorNogueira, Carlos
dc.contributor.authorMargarido, F.
dc.date.accessioned2010-03-24T10:46:18Z
dc.date.available2010-03-24T10:46:18Z
dc.date.issued2009-11-10
dc.description.abstractThe leaching of metals contained in spent Zn-MnO2 batteries and electric arc furnace (EAF) dusts using sulfuric acid solutions was studied, in order to evaluate the feasibility of simultaneous treatment of both wastes by a hydrometallurgical process. In both residues, a substantial quantity of zinc was solubilized (about 100% in batteries and 70-80% in EAF dusts) in diluted acid solutions and room temperature, corresponding to the reaction of zinc oxide species. Other species were more refractory to the chemical attack, namely the manganese (III or IV) oxides in batteries and the zinc ferrite in dusts, requiring higher temperatures (e.g. 90ºC) and higher leachant concentrations. Lead present in EAF dusts was not solubilized in sulfate media, thus remaining in the leach residue. Results seem to confirm the possibility of treatment of both zinc-containing residues by the same hydrometallurgical process, eventually involving two leaching stages – diluted acid leaching and hot acid leaching – followed by solution purification through iron precipitation and Zn/Mn separation and recovery. Concerning lead, a second leaching circuit in chloride media could be developed for its potential recovery.pt
dc.identifier.citationPedrosa, Fátima; Cabral, Marta; Nogueira, C. A.; Margarido, F.; Leaching behavior of several zinc rich residues in a hydrometallurgical recycling process. Comunicação apresentada ao: WRF’09 – World Recycling Forum ’09: Proceedings of 4th Intern. Conf. and Exhibition, Shanghai, China, 2009, November 10–13, 2p.pt
dc.identifier.urihttp://hdl.handle.net/10400.9/590
dc.language.isoengpt
dc.subjectZinc residuespt
dc.subjectSpent batteriespt
dc.subjectEAF dustspt
dc.subjectRecyclingpt
dc.subjectLeachingpt
dc.titleLeaching behavior of several zinc rich residues in a hydrometallurgical recycling processpt
dc.typeconference object
dspace.entity.typePublication
oaire.citation.conferencePlaceShangai, Chinapt
oaire.citation.titleWRF’09 – World Recycling Forum ’09pt
person.familyNamePedrosa
person.familyNameNogueira
person.givenNameFátima
person.givenNameCarlos
person.identifier.ciencia-id011E-FCCD-4FA6
person.identifier.orcid0000-0002-0479-822X
person.identifier.orcid0000-0003-2949-5046
person.identifier.ridA-4926-2013
person.identifier.scopus-author-id7006686159
rcaap.rightsopenAccesspt
rcaap.typeconferenceObjectpt
relation.isAuthorOfPublication2ce2b103-1205-4c2a-8799-fd7d9f5f7800
relation.isAuthorOfPublicationb4222458-c0fc-4926-9d9a-e3cf9ae1e7e3
relation.isAuthorOfPublication.latestForDiscoveryb4222458-c0fc-4926-9d9a-e3cf9ae1e7e3

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