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Thermal Stability and Irradiation Resistance of (CrFeTiTa)70W30 and VFeTiTaW High Entropy Alloys

datacite.subject.fosEngenharia e Tecnologia::Engenharia dos Materiais
datacite.subject.fosCiências Naturais::Ciências Físicas
datacite.subject.sdg12:Produção e Consumo Sustentáveis
datacite.subject.sdg13:Ação Climática
dc.contributor.authorPereira, André
dc.contributor.authorMartins, Ricardo
dc.contributor.authorMonteiro, Bernardo
dc.contributor.authorCorreia, Jose B.
dc.contributor.authorGalatanu, Andrei
dc.contributor.authorCatarino, Norberto
dc.contributor.authorJenus, Petra
dc.contributor.authorDias, Marta
dc.date.accessioned2025-07-23T15:56:12Z
dc.date.available2025-07-23T15:56:12Z
dc.date.issued2025-03
dc.description.abstractABSTRACT: Nuclear fusion is a promising energy source. The International Thermonuclear Experimental Reactor aims to study the feasibility of tokamak-type reactors and test technologies and materials for commercial use. One major challenge is developing materials for the reactor's divertor, which supports high thermal flux. Tungsten was chosen as the plasma-facing material, while a CuCrZr alloy will be used in the cooling pipes. However, the gradient between the working temperatures of these materials requires the use of a thermal barrier interlayer between them. To this end, refractory high-entropy (CrFeTiTa)70W30 and VFeTiTaW alloys were prepared by mechanical alloying and sintering, and their thermal and irradiation resistance was evaluated. Both alloys showed phase growth after annealing at 1100 degrees C for 8 days, being more pronounced for higher temperatures (1300 degrees C and 1500 degrees C). The VFeTiTaW alloy presented greater phase growth, suggesting lower microstructural stability, however, no new phases were formed. Both (as-sintered) alloys were irradiated with Ar+ (150 keV) with a fluence of 2.4 x 1020 at/m2, as well as He+ (10 keV) and D+ (5 keV) both with a fluence of 5 x 1021 at/m2. The morphology of the surface of both samples was analyzed before and after irradiation showing no severe morphologic changes, indicating high irradiation resistance. Additionally, the VFeTiTaW alloy presented a lower deuterium retention (8.58%) when compared to (CrFeTiTa)70W30 alloy (14.41%).eng
dc.identifier.citationPereira, A., Martins, R., Monteiro, B., Correia, J. B., Galatanu, A., Catarino, N., Belec, P. J. & Dias, M. (2025). Thermal Stability and Irradiation Resistance of (CrFeTiTa)70W30 and VFeTiTaW High Entropy Alloys. In: Materials, 2025, vol. 18 (5), article 1030. https://doi.org/10.3390/ma18051030
dc.identifier.doi10.3390/ma18051030
dc.identifier.eissn1996-1944
dc.identifier.urihttp://hdl.handle.net/10400.9/6002
dc.language.isoeng
dc.peerreviewedyes
dc.publisherMDPI
dc.relationInstitute for Plasmas and Nuclear Fusion
dc.relation.hasversionhttps://www.mdpi.com/1996-1944/18/5/1030
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subjectHigh entropy alloys
dc.subjectMechanical properties
dc.subjectMicrostructure
dc.subjectThermal barriers
dc.titleThermal Stability and Irradiation Resistance of (CrFeTiTa)70W30 and VFeTiTaW High Entropy Alloyseng
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleInstitute for Plasmas and Nuclear Fusion
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F50010%2F2020/PT
oaire.citation.issue5
oaire.citation.titleMaterials
oaire.citation.volume18
oaire.fundingStream6817 - DCRRNI ID
oaire.versionhttp://purl.org/coar/version/c_970fb48d4fbd8a85
person.familyNameMartins
person.familyNameMonteiro
person.familyNameCorreia
person.familyNameGalatanu
person.familyNameCatarino
person.familyNameJenus
person.familyNameDias
person.givenNameRicardo
person.givenNameBernardo
person.givenNameJose B.
person.givenNameAndrei
person.givenNameNorberto
person.givenNamePetra
person.givenNameMarta
person.identifier.ciencia-idC31C-D617-6377
person.identifier.ciencia-id0E13-5F70-9D8A
person.identifier.orcid0000-0001-7768-5704
person.identifier.orcid0000-0001-6434-365X
person.identifier.orcid0000-0002-8314-0695
person.identifier.orcid0000-0001-8474-8259
person.identifier.orcid0000-0003-3879-1533
person.identifier.orcid0000-0002-1926-479X
person.identifier.orcid0000-0001-6797-7711
person.identifier.scopus-author-id7202364148
person.identifier.scopus-author-id35415989000
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
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