Volume 107 (2020) - Fascículo Especial III (Projeto Explora - Definição de novos vetores de conhecimento geológico, geofísico e geoquímico para a região setentrional de Neves-Corvo)
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Percorrer Volume 107 (2020) - Fascículo Especial III (Projeto Explora - Definição de novos vetores de conhecimento geológico, geofísico e geoquímico para a região setentrional de Neves-Corvo) por autor "Araújo, Vítor"
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- Geochemistry of Iberian Pyrite Belt Portuguese sector massive sulfide deposits-related volcanic rocks. Considerations on hydrothermal alteration, petrology and tectonic evolutionPublication . Morais, Igor; Albardeiro, Luís; Batista, Maria Joao; Matos, João Xavier; Solá, A. Rita; de Oliveira, Daniel Pipa Soares; Salgueiro, Rute; Araújo, Vítor; Pacheco, NelsonABSTRACT: A geochemical compilation database of the main volcanic units of the Volcano-Sedimentary Complex (VSC) of the Iberian Pyrite Belt (IPB), one of the largest provinces of massive sulfides on a global scale, is presented and discussed. For this purpose, we used several mineral exploration rock geochemistry databases from six IPB areas, namely Cercal, Lagoa Salgada, Lousal, Aljustrel, Neves-Corvo and Chança, regarding unaltered/hydrothermaly altered felsic volcanic units interbedded in the Famennian-Late Visean volcano-sedimentary sequences of the VSC. Volcanic rocks within the Phyllite-Quartzite Formation (Givetian-Famennian) IPB basement were also considered. From this, Neves-Corvo sector rhyolites (Rhyolite type 1 and 2) present the most intense hydrothermal alteration, directly related with the age of mineralization and coeval with hosted VSC sedimentary formations. Similar cases were also observed in the volcanic units hosting Lagoa Salgada, Chança and Aljustrel Volcanic-hosted massive sulfide (VHMS) deposits. The variety of felsic and intermediate volcanic rocks in the IPB (and within each sector) reflect different petrogenetic processes and/or distinct crustal sources. Application of Zr vs TiO2 binary diagrams allows to define three main trends of andesitic (Lagoa Salgada and Chança sectors), dacitic-rhyodacitic (Aljustrel sector) and rhyolitic (Cercal, Neves-Corvo, Aljustrel and Lousal sectors) composition. Cercal rhyolites are the most evolved felsic rocks (Zr/TiO2 ≈ 1562), followed by Neves-Corvo rhyolites (Zr/TiO2 ≈ 936), Lousal (Zr/TiO2 ≈ 845) and Aljustrel (Zr/TiO2 ≈ 840). In addition, four distinct compositional clusters can be distinguished based on Al2O3/TiO2 vs Zr/TiO2 and Al2O3/Zr vs TiO2/Zr ratios according to its nature as, rhyolitic, rhyodacitic/dacitic and andesitic, probably reflecting differential partial melting rates. Ybn vs La/Yb(n) diagram ratio indicates that Neves-Corvo (mainly 2 types of rhyolites), Aljustrel (Tufo da Mina rhyolitic unit), as well as Lagoa Salgada sector rhyolites are projected along FIIIa and FIIIb rhyolite fields considered of higher metalliferous potential in the IPB, once their petrogenetic processes are considered ideal to trigger, sustain and host hydrothermal systems and consequently VHMS deposits. Future work, combining geochemical characterization of each volcanic unit with their stratigraphic positioning, is essential in order to achieve a correct correlation between the different sectors and, is therefore, a useful tool in IPB mineral exploration and drill-hole data correlation.
- Geological correlation of Neves-Corvo Mine and Pomarão Antiform sequences (Iberian Pyrite Belt, Portugal)Publication . Albardeiro, Luís; Matos, João Xavier; Mendes, Márcia; Solá, A. Rita; Pereira, Zélia; Morais, Igor; Salgueiro, Rute; Pacheco, Nelson; Araújo, Vítor; Oliveira, José TomásABSTRACT: A geological correlation between Neves-Corvo (NC) and Pomarão antiforms is attempted. These regional scale major sequences are easily correlated but, at local scale, facies and age differences stand out. Stratigraphy includes: i) the Phyllite-Quartzite Group with identical paleogeography setting and similar late Famennian ages for uppermost levels (LL to LN miospore biozones in Pomarão and NC respectively). ii) the Volcano-Sedimentary Complex shows some discrepancyconcerning the age distribution of the felsic volcanic rocks (ca. 356-330for Pomarão and ca. 365-346 Ma for all NC area) while sediments rangefrom mid-Famennian to late Visean age (VH to NM Miospore Biozonefor NC). iii); the Baixo Alentejo Flysch Group (late Visean NM MiosporeBiozone onwards in NC), covering the previous sequences and beingslightly older than the uppermost volcanic rocks of Pomarão. Thecorrelation between these two structures is supported by geology andisotopic/biozone ages and favours exploration scenarios in both regions.