Volume 107 (2020) - Fascículo Especial III (Projeto Explora - Definição de novos vetores de conhecimento geológico, geofísico e geoquímico para a região setentrional de Neves-Corvo)
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- Carlos Inverno, an economic geologist in the service of sciencePublication . de Oliveira, Daniel Pipa SoaresABSTRACT: Carlos Manuel Clériguinho Inverno (born on 7/3/1953, Lisbon) was awarded degrees of BSc and License in Geology by the Univ. of Lisbon, Portugal, in 1973 and 1975, respectively. Under the supervision of Prof. Richard W. Hutchinson, a PhD in Geology (sp. Geochemistry) by the Colorado School of Mines followed in 1991, which granted equivalence as Doutor em Geologia (Metalogenia) by the Univ. of Lisbon in 1992. He was a postdoctoral researcher at the Univ. of Tasmania and its Centre for Ore Deposit Research (CODES) in 2000-2001 (advisor, Prof. Michael Solomon) and earned Tenure (Agregação) at the Univ. of Lisbon in 2008.
- Geochemical exploration and assessment of environmental impacts in the Portuguese sector of the Iberian Pyrite BeltPublication . Batista, Maria Joao; Mateus, A; Matos, João Xavier; Gonçalves, Mário A.; Figueiras, Jorge; Abreu, Maria Manuela; Luz, FilipaABSTRACT: This work intends to briefly report the history and application of geochemical exploration techniques in the Iberian Pyrite Belt (IPB). The use of geochemistry in IPB for exploration purposes started in 1950s. Together with geophysics, the soil geochemical exploration surveys performed over several decades were responsible for important discoveries such as Carrasco and Feitais ore-bodies. However, the continuous development of analytical methods and the progress in data processing/modelling led to significant changes in the planning of sampling surveys, and their specific objectives, as well as in the accuracy of geochemical anomalies definition and corresponding interpretation. As a consequence, the number of samples involved in each survey was significantly reduced, but the chemical elements analysed with improved detection limits were considerably extended; additionally, geochemical anomalies were better resolved. Notwithstanding this evolution, data obtained in early soil geochemical surveys (notably by the Serviço de Fomento Mineiro) are still useful in the development of preliminary approaches at a regional scale. Over the years, many studies were made for exploration and environmental assessments, the most relevant of them reported in this chapter. Natural distributions of chemical elements were also identified in these studies as background (if pristine conditions are present) or baseline (depending how disturbed is the area covered by the sampling survey) values. Large part of IPB was, and still is, subjected to poly-metallic mineral exploration or mining, being also the focus of environmental evaluation and/or remediation projects on particular areas that, being the target of long-lasting human intervention, represent paradigmatic case-study examples. The exploration and exploitation works carried out by national and foreign private companies were, and still are, very important for innovative achievements in IPB along with copious contributions from the Portuguese R&D public institutions. Presently, LNEG possesses a vast quantity of geochemical data that can be provided for companies that wish to start their activity in the IPB; some of these datasets are compiled to a unique integrative map also presented in this work. Stream-sediments geochemistry, hydrogeochemistry and lithogeochemistry (of outcropping rock and drill-core samples) represent also important sources of geochemical data in regional or detailed studies over specific target areas in the IPB. However, these techniques are beyond the scope of the present paper which aimed at providing a general overview of the importance of soil geochemistry studies in the current knowledge of the IPB.
- Geochemistry of Iberian Pyrite Belt Portuguese sector massive sulfide deposits-related volcanic rocks. Considerations on hydrothermal alteration, petrology and tectonic evolutionPublication . Morais, Igor; Albardeiro, Luís; Batista, Maria Joao; Matos, João Xavier; Solá, A. Rita; de Oliveira, Daniel Pipa Soares; Salgueiro, Rute; Araújo, Vítor; Pacheco, NelsonABSTRACT: A geochemical compilation database of the main volcanic units of the Volcano-Sedimentary Complex (VSC) of the Iberian Pyrite Belt (IPB), one of the largest provinces of massive sulfides on a global scale, is presented and discussed. For this purpose, we used several mineral exploration rock geochemistry databases from six IPB areas, namely Cercal, Lagoa Salgada, Lousal, Aljustrel, Neves-Corvo and Chança, regarding unaltered/hydrothermaly altered felsic volcanic units interbedded in the Famennian-Late Visean volcano-sedimentary sequences of the VSC. Volcanic rocks within the Phyllite-Quartzite Formation (Givetian-Famennian) IPB basement were also considered. From this, Neves-Corvo sector rhyolites (Rhyolite type 1 and 2) present the most intense hydrothermal alteration, directly related with the age of mineralization and coeval with hosted VSC sedimentary formations. Similar cases were also observed in the volcanic units hosting Lagoa Salgada, Chança and Aljustrel Volcanic-hosted massive sulfide (VHMS) deposits. The variety of felsic and intermediate volcanic rocks in the IPB (and within each sector) reflect different petrogenetic processes and/or distinct crustal sources. Application of Zr vs TiO2 binary diagrams allows to define three main trends of andesitic (Lagoa Salgada and Chança sectors), dacitic-rhyodacitic (Aljustrel sector) and rhyolitic (Cercal, Neves-Corvo, Aljustrel and Lousal sectors) composition. Cercal rhyolites are the most evolved felsic rocks (Zr/TiO2 ≈ 1562), followed by Neves-Corvo rhyolites (Zr/TiO2 ≈ 936), Lousal (Zr/TiO2 ≈ 845) and Aljustrel (Zr/TiO2 ≈ 840). In addition, four distinct compositional clusters can be distinguished based on Al2O3/TiO2 vs Zr/TiO2 and Al2O3/Zr vs TiO2/Zr ratios according to its nature as, rhyolitic, rhyodacitic/dacitic and andesitic, probably reflecting differential partial melting rates. Ybn vs La/Yb(n) diagram ratio indicates that Neves-Corvo (mainly 2 types of rhyolites), Aljustrel (Tufo da Mina rhyolitic unit), as well as Lagoa Salgada sector rhyolites are projected along FIIIa and FIIIb rhyolite fields considered of higher metalliferous potential in the IPB, once their petrogenetic processes are considered ideal to trigger, sustain and host hydrothermal systems and consequently VHMS deposits. Future work, combining geochemical characterization of each volcanic unit with their stratigraphic positioning, is essential in order to achieve a correct correlation between the different sectors and, is therefore, a useful tool in IPB mineral exploration and drill-hole data correlation.
- Geological correlation of Neves-Corvo Mine and Pomarão Antiform sequences (Iberian Pyrite Belt, Portugal)Publication . Albardeiro, Luís; Matos, João Xavier; Mendes, Márcia; Solá, A. Rita; Pereira, Zélia; Morais, Igor; Salgueiro, Rute; Pacheco, Nelson; Araújo, Vítor; Oliveira, José TomásABSTRACT: A geological correlation between Neves-Corvo (NC) and Pomarão antiforms is attempted. These regional scale major sequences are easily correlated but, at local scale, facies and age differences stand out. Stratigraphy includes: i) the Phyllite-Quartzite Group with identical paleogeography setting and similar late Famennian ages for uppermost levels (LL to LN miospore biozones in Pomarão and NC respectively). ii) the Volcano-Sedimentary Complex shows some discrepancyconcerning the age distribution of the felsic volcanic rocks (ca. 356-330for Pomarão and ca. 365-346 Ma for all NC area) while sediments rangefrom mid-Famennian to late Visean age (VH to NM Miospore Biozonefor NC). iii); the Baixo Alentejo Flysch Group (late Visean NM MiosporeBiozone onwards in NC), covering the previous sequences and beingslightly older than the uppermost volcanic rocks of Pomarão. Thecorrelation between these two structures is supported by geology andisotopic/biozone ages and favours exploration scenarios in both regions.
- Geophysical surveys in the Portuguese sector of the Iberian Pyrite Belt: a global overview focused on the massive sulphide exploration and geologic interpretationPublication . Matos, João Xavier; Carvalho, João; Represas, Patricia; Batista, Maria Joao; Sousa, P.; Ramalho, Elsa; Marques, Fábio; Morais, Igor; Albardeiro, Luís; Gonçalves, Pedro; Dias, P.ABSTRACT: The application of geophysical techniques to massive sulphide deposits exploration has proven to be a success in the Iberian Pyrite Belt (IPB) metallogenetic province, both in Portugal and in Spain. Several hidden deposits were discovered through the interpretation of geological models, supported by geophysical data collected in land and airborne surveys, as well as applied using down hole techniques in selected drill holes. This paper presents an overview of the methodologies applied in Portugal in the South Portuguese Zone (SPZ) geological domain, where the IPB is included, mostly by the LNEG and mining companies, with emphasis on the interpretation of the regional gravity, magnetometry and radiometry surveys, published in 1/400 000 scale by the EXPLORA/Alentejo2020 Project. In this regional mapping program, the large volume of data collected by LNEG and mining companies since the 1960’s was compiled and processed. The integrated interpretation and correlation between these methods will enable a better planning of new IPB exploration investments. IPB Volcano-Sedimentary Complex (VSC, Famennian to Late Visean age) lineaments are well defined in the gravity and magnetic fields along the IPB western region (e.g. Alcoutim/Neves-Corvo/Montinho/Sesmarias/Lousal/Caveira). Aeromagnetic data also reflect deep and large anomalies related with the SPZ basement. A rock density database is presented and used to interpret the gravity data. Radiometric map (Natural Radioactivity), based mostly in airborne radiometric surveys, show contrasts between rocks in Paleozoic, Mesozoic and Cenozoic formations and correlations with geological and hydrothermal mapping are highlighted. The use of geophysical techniques is particularly critical in areas where VSC is concealed by younger sediments (e.g. Baixo Alentejo Flysch Group and/or Cenozoic formations), allowing the selection of target areas. Case studies are discussed based on electromagnetic, seismic and magnetotelluric methods and on the high mineral potential of defined targets. Multilayered data correlation (geophysics including petrophysical data, geochemistry and stratigraphic high-resolution models) is a key prospecting methodology and is essential for the accurate modelling of ore horizons and geological structures. Considering the IPB potential for VMS deposits, including the possible discovery of new giant (> 200 Mt) deposits, an increase of investment in new geophysical methods can be predicted. LNEG development of R&D projects such as EXPLORA/Alentejo2020 and SmartExplorationTM/H2020 also contribute to a favourable setting in the province, both in near mining and green fields scenarios. Thus, new discoveries are expected, like others made in the recent times in the IPB Portuguese sector, such as Lagoa Salgada (SFM, 1992, SFM; Redcorp/EDM, 2011; Redcorp/Ascendant/EDM, 2017), Semblana (Somincor-AGC-Lundin Mining, 2010), Monte Branco (Somincor-Lundin Mining, 2012) and Sesmarias (Maepa/Avrupa, 2014). The importance of these data goes beyond the mineral exploration purpose. Since some of them use rock and mineral physical properties that can be related with environmental contamination (e.g. radiometry and magnetics) they can also be used in geochemical background studies, acid mine drainage and metal dispersion. Therefore, they can also promote a deeper knowledge in other areas of research related with environment preservation.
- Mineral sustainability of the Portuguese sector of the Iberian Pyrite BeltPublication . de Oliveira, Daniel Pipa Soares; Batista, Maria Joao; Matos, João Xavier; Silva, TeresaABSTRACT: The Iberian Pyrite Belt (IPB) is one of the most important volcanogenic massive sulphide districts in the world and has been mined during more than 5 000 years. Its early and rich mining history is known to have been very important in Tartessian and Roman times when working the oxidation and cementation zones of the deposits for gold, silver and copper preferentially took place in the outcropping deposits. Even after continuous metal extraction for more than 5000 years, the IPB retains exceptionally large metal reserves. The IPB remains a hub of continued research and exploration and as a consequence, sulphide reserves in the IPB are being continuously increased with new discoveries: Aguas Teñidas, Lagoa Salgada, Las Cruces, Migollas, Masa Valverde, Vallejin, Las Cruces, Semblana and Monte Branco, La Magdalena and Sesmarias. While today's mining activities are focused in massive and stockwork ores and confined to 7 Portuguese and Spanish districts: Aljustrel, Neves-Corvo, Sotiel-Migollas, Rio Tinto, Aznalcollar- Los Frailes, Tharsis and Las Cruces, the IPB retains a large potential for non-traditional (or accessory ores) products. In light of the critical raw materials and the concepts of the circular economy, the IPB has the potential to be an important source of accessory metals; sourced from both primary and secondary ores and mine waste, that fall both in the strategic and critical domains. Metals like indium, selenium, germanium, rhenium and the precious metals are targets to seek in future exploration scenarios within the IPB, particularly in the Portuguese sector and in key near mining areas.
- Multispectral and hyperspectral remote sensing as a source of knowledge in the Portuguese sector of the Iberian Pyrite BeltPublication . Quental, Lídia; Gonçalves, Pedro; de Oliveira, Daniel Pipa Soares; Batista, Maria Joao; Matos, João Xavier; Sousa, A. J.; Marsh, Stuart; Carreiras, Joao; Dias, Ruben PereiraABSTRACT: Remote sensing is an invaluable tool to increase geological and mining knowledge, due to its screening view and variable discrimination and identification capabilities of the target materials. In this study an overview of remote sensing research developed and ongoing within the Portuguese sector of the Iberian Pyrite Belt (PSIPB) since 2000 is given. Multispectral and hyperspectral datasets were processed using hybrid methods, related both to general and detailed characterization, to: 1) support geological, mineral and hydrothermal mapping, 2) generate products derived from multivariate analysis and band ratios, 3) enhance correlation with radiometric data, 4) provide elements for environmental assessment concerning mining activity, 5) map Acid Mine Drainage (AMD) based on spectral field signatures, 6) quantify AMD based on high correlation mineralogical mapping, and 7) monitor AMD. The results highlight the importance of the quantitative digital support given by remote sensing tools within the Portuguese Sector of the Iberian Pyrite Belt (PSIPB), ruled by georesource exploitation in different stages of the Mine Lyfe Cycle.
- Preliminary dating of the Vale de Parreiras Formation of the late Famennian age, Iberian Pyrite Belt, Portugal, based on palynomorphsPublication . Mendes, Márcia; Pereira, Zélia; Albardeiro, Luís; Matos, João XavierABSTRACT: New palynostratigraphic data were obtained from phyllites interbedded with quartzwackes of the Vale de Parreiras Formation, located to the south of the Grândola Fault in the Azinheira de Barros region, Portugal. The studied outcrops are located in the eastern bank of the Sado river. A mid-late Famennian age has been assigned based on significant presence of the key miospore species Grandispora cf. cornuta and Rugospora flexuosa, indicating a VCo Miospore Biozone for the Vale de Parreiras Formation. This age is older than previously considered for this formation, even despite the lack of palaeontological information and geochronological age determinations. This new attained palynological age provides helpful informations for the interpretation of regional tectonic structures. Also, its stratigraphic position could be reinterpreted and correlated to other late Famennian age units of Iberian Pyrite Belt, for instance, to the Phyllite-Quartzite Group. The new palynological age indicates that the Vale Parreiras Formation lithologies were deposited and belong to the same palaeogeographic realm as the former group during Late Devonian times. It may also suggest important post Variscan uplift of the Iberian Pyrite Belt in the area east of the Corona-Sado Fault and south of the Grândola Fault. These results also indicate a significant exposure of the mid-late Famennian basement wich can be considered a less favourable scenario to mineral exploration in this Iberian Pyrite Belt sector.