Browsing by Issue Date, starting with "2008-09-03"
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- Sulphate reducing bacteria for metals bioremediationPublication . Duarte, José Cardoso; Sàágua, M. C.; Paixão, Susana M.; Baeta-Hall, Lina; Costa, Clara
- Perfilometria óptica baseada em recuperação de fase.Publication . Coelho, João M. P.; Domingues, C.; Monteiro, Fernando; Abreu, Manuel A.
- Electrochemical energy conversion in direct methanol fuel cellsPublication . Rangel, C. M.; Silva, R. A.; Verget, J.; Pinto, A.M.F.R.Direct methanol fuel cells (DMFCś) are promising candidates as portable power sources due to their lower weight, volume and high-energy density. They can potentially provide an energy content that exceeds current battery technology, with the possibility of instantaneous recharge. However, DMFCś have several serious drawbacks such as slow methanol oxidation kinetics, poisoning by CO of the catalyst surface, the high methanol crossover through the polymer membrane, the high costs of the Nafion membrane and catalyst. The flowing streams of fuel and oxidizer need to be evenly distributed over the entire surface of the catalyst layer in order to achieve a good performance together with an efficient removal of reaction products. This is achieved through the optimal design of the flow field. In this work the effect of flow field design on cell performance is studied, using polarization curves. A testing fuel cell was designed and implemented consisting of two stainless steel end plates, two sets of graphite collector plates, two carbon cloth diffusion layers, two catalyst layers of platinum black (0.70 mg.cm-2 and 0.75 mg.cm-2 Pt on cathode and anode, respectively) and an electrolyte polymer membrane (Nafion 117). Pt-Ru catalyst on the anode with a load of 4 mgcm-2 of catalyst was also studied. The active surface area of the cell is 25 cm2. An own built fuel cell and a Lyntech testing station were used in this work. The effects of temperature, methanol concentration, feeding flow rates of fuel and flow field design on the cell performance were studied. Results showed that the performance of the fuel cell increases with increase in cell temperature due to improvement in methanol oxidation kinetics and cathode kinetics, as indicated by polarization curves. The effect of temperature is complex; the oxygen partial pressure decreases with temperature increase due to the increase in vapor partial pressure, which causes decreases in the open-cell voltage and increases the concentration overpotential; the rate of methanol crossover increases with temperature, so the cell performance decreases; water transfer from anode to cathode through the membrane increases with temperature and the additional water increases the liquid water fraction in both the cathode catalyst and diffusion layers, thus causing an increase in concentration polarization. Increase in methanol concentration affected the performance of the DMFC, as expected due to a higher methanol crossover with higher concentrations. The methanol transferred from the anode to the cathode through the polymer electrolyte membrane is oxidized at the platinum electrocatalyst and causes a mixed potential, which lowers the cathode performance and thus the overall cell voltage output. The effect of the flow field design, single serpentine and parallel, on cell performance was also investigated. The serpentine flow field was better than the parallel design. The obtained results point towards an enhancement in the mass transfer of methanol improving the cell performance. Another important issue is the eventual blocking of the flow channels, by CO2, at high current densities. A reduction of the effective contact area between the fuel (methanol) and the gas diffusion layer is expected, as CO2 gas bubbles accumulate in the channels, bearing implications in the continuous supply of methanol to the catalyst sites through the gas diffusion layer. This is less likely to occur with the serpentine design. Cathode kinetics indicates slightly lower methanol crossover and better voltage efficiency at low current densities. Comparison is made with results obtained for the two different catalyst layers used emphasizing the effect of Ru.
- Interferometria no infravermelho médioPublication . Silva, Catarina; Coelho, João M. P.; Monteiro, Fernando; Abreu, Manuel A.; Rebordão, José Manuel
- Kinetics of a packed-bed bacth reactor for the treatment of olive oil wastewaters from a Portuguese millPublication . Ribeiro, Belina; Correia, Anabela; Paixão, Susana M.; Baeta-Hall, Lina; Sàágua, M. C.; Duarte, José CardosoOlive oil production is a traditional agricultural industry in Mediterranean countries and Portugal is one of the ten major producers. This industry generates an effluent, olive mill wastewater. This effluent does not undergo any treatment and is usually stored in evaporation lagoons or spread on the land. This can have a negative impact in the environment since this effluent has a high level of organic matter leading to a high chemical oxygen demand. In addition it has also a high content of polyphenols that contributes to the ecotoxicity of this effluent.Different techniques for the treatment of these wastewaters have been studied. In this work a 60 litre vessel was filled with a packaging of plastic material consisting of a cubic geometry (Biological Carrier Media from Rauschert). The non-inoculated reactor was filled with effluent from an olive mill farm (from Alfândega da Fé, Trás-os-Montes) and the effluent was re-circulated daily for homogeneity. COD, colour, nitrogen, solids and phosphorous were measured to follow the evolution of the system. Microbial composition and polyphenols were also evaluated. As an indicator of the microbial activity in the reactor, lipase activities were measured. Ecotoxicity tests were carried out to follow the detoxification capacity of the system as well as its potential for using in the treatment of this type of agroindustrial effluent.
- Modelação do aquecimento de células por radiação laserPublication . Vilhena, H.; Coelho, João M. P.; Rebordão, José Manuel
- Metals recovery from mine lead concentrates:screening of bioleaching microbial communitiesPublication . Duarte, José Cardoso; Sàágua, M. C.; Paixão, Susana M.; Baeta-Hall, Lina; Nogueira, Carlos; Pereira, Paula Sá; Anselmo, Ana