Browsing by Issue Date, starting with "2021-04"
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- Late Permian palaeoenvironmental evolution of the Matinde Formation in the Muarádzi Sub-basin, Moatize-Minjova Basin, MozambiquePublication . Lopes, Gilda; Pereira, Zélia; Fernandes, Paulo; Mendes, Márcia; Marques, João; Jorge, Raul CG SantosABSTRACT:A multidisciplinary study involving lithofacies analysis, palynofacies, and palynology is presented for the Muaradzi Sub-basin. This sub-basin is part of the Moatize-Minjova Basin (MMB), an important Karoo aged coalfield in Mozambique. A total of 99 core samples from 3 coal exploration boreholes (DW11, DW21, and DW141) were analysed and all the successions were assigned a Lopingian age based on palynology. According to the data, in the Muar ' adzi Sub-basin, a vast lowland fluvial setting existed with floodplains and wetlands, in an area controlled by tectonic movements associated with a continental rifting phase. Typical vegetation of the Glossopteris Province is recorded in the palynological assemblages of this sub-basin, which allowed for the characterization of a flora dominated by glossopterids (Protohaploxypinus and Striatopodocarpites) and gymnosperm pollen (Alisporites). Other palynomorphs revealed the presence of gingkoales, ferns (Filicopsida), sphenopsids, and lycopsids in the area, indicating a typical lowland setting. Humid and warm climates, associated with higher CO2 atmospheric levels, promoted the growth of widespread vegetation that led to the development of the thick coal beds in anoxic to dysoxic depositional environments.
- The critical raw materials issue between scarcity, supply risk, and unique propertiesPublication . Girtan, Mihaela; Wittenberg, Antje; Grilli, Maria Luisa; De Oliveira, Daniel Pipa Soares; Giosuè, Chiara; Ruello, Maria LetiziaABSTRACT: This editorial reports on a thorough analysis of the abundance and scarcity distribution of chemical elements and the minerals they form in the Earth, Sun, and Universe in connection with their number of neutrons and binding energy per nucleon. On one hand, understanding the elements’ formation and their specific properties related to their electronic and nucleonic structure may lead to understanding whether future solutions to replace certain elements or materials for specific technical applications are realistic. On the other hand, finding solutions to the critical availability of some of these elements is an urgent need. Even the analysis of the availability of scarce minerals from European Union sources leads to the suggestion that a wide-ranging approach is essential. These two fundamental assumptions represent also the logical approach that led the European Commission to ask for a multi-disciplinary effort from the scientific community to tackle the challenge of Critical Raw Materials. This editorial is also the story of one of the first fulcrum around which a wide network of material scientists gathered thanks to the support of the funding organization for research and innovation networks, COST (European Cooperation in Science and Technology).
- Performance assessment of a building-integrated photovoltaic thermal system in a Mediterranean climate: an experimental analysis approachPublication . Bot, Karol; Aelenei, Laura Elena; Goncalves, Helder; Gomes, Maria da Glória; Silva, Carlos SantosABSTRACT: The experimental investigation of building-integrated photovoltaic thermal (BIPVT) solar systems is essential to characterise the operation of these elements under real conditions of use according to the climate and building type they pertain. BIPVT systems can increase and ensure energy performance and readiness without jeopardising the occupant comfort if correctly operated. The present work presents a case study's experimental analysis composed of a BIPVT system for heat recovery located in a controlled test room. This work contribution focuses on the presentation of the obtained measured value results that correspond to the BIPVT main boundary conditions (weather and room characteristics) and the thermal behaviour and performance of the BIPVT system, located in the Solar XXI Building, a nZEB exposed to the mild Mediterranean climate conditions of Portugal.
- Interplay of tectonics and magmatism during post-rift inversion on the central West Iberian Margin (Estremadura Spur)Publication . Pereira, Ricardo; Rosas, Filipe M.; Mata, João; Represas, Patricia; Escada, Cláudia; Silva, BeatrizABSTRACT: The combined effects of post-rift magma emplacement and tectonic inversion on the hyper-extended West Iberian Margin are unravelled in detail using multichan nel 2D/3D seismic data. The Estremadura Spur, acting as an uplifted crustal block bounded by two first-order transfer zones, shows evidence of four post-rift tectonic events each with a distinctive seismic-stratigraphic response that can be used to dem onstrate the tectono-magmatic interplay, namely: (a) the Campanian onset of mag matism (including the Fontanelas Volcano, the widespread evidence of multiple sill complexes and the detailed description of a >20 km long laccolith, the Estremadura Spur Intrusion; (b) the Campanian-Maastrichtian NE-SW event pervasively affecting the area, resulting in regional uplift, reverse faulting and folding; (c) the Paleocene mid Eocene inversion that resulted in widespread erosion and; (d) the Oligocene-mid Miocene evidence of rejuvenated NW-SE inversion marked by crestal faulting and forced-fault folding establishing the final geometry of the area. The distinct deforma tion styles within each tectonic phase document a case of decoupled deformation be tween Late Cretaceous and Tertiary units, in response to the predominant stress field evolution, revealing that the magnitude of Late Cretaceous inversion is far more sig nificant than the one affecting the latter units. A detailed analysis of the laccolith and its overburden demonstrate the distinct deformation patterns associated both with magma ascent (including extensional faulting, forced-folding and concentric reverse faulting) and its interference as a rigid intrusive body during subsequent transpres sive inversion. This reinforces the role that the combined tectono-magmatic events played on the margin. Also analysed is the wider impact of post-rift magmatism and the associate emplacement of sub-lithospheric magma on the rheology of a thinned continental crust. This takes into account the simultaneous tectonic inversion of the margin, the implied alternative views on characteristic heat flow, and on how these can be incorporated in source rock organic maturity modelling.
- Geology of the Macao Special Administrative Region (China)Publication . Quelhas, Pedro; Borges, Ricardo; Dias, Ágata Alveirinho; Ribeiro, Maria Luísa; Costa, Pedro; Mata, JoãoABSTRACT: A 1:12,000 geological map of the Macao Special Administrative Region has been produced through detailed field work supported by petrographic, mineralogical, geochronological and geochemical data obtained in previous studies. This map aims to represent a reliable tool to understand the geological evolution of the region and for management of the territory. The geology of Macao is dominated by two groups of Jurassic granitic rocks belonging to an intrusive suite located along the coast of Southeast China: Macao Group I (MGI: 164.5 ± 0.6 to 162.9 ± 0.7 Ma) and Macao Group II (MGII: 156.6 ± 0.2 to 155.5 ± 0.8 Ma), including the associated microgranite, aplite and pegmatite dikes and quartz veins. Remnants of the metasedimentary wall-rock are present as Devonian xenoliths enclosed within the granites. Younger Jurassic to Cretaceous andesite to dacite dikes (150.6 ± 0.6 to <120 Ma) intrude the granitic rocks. Additionally, Quaternary sedimentary deposits cover the older lithologies.
- Effect of saccharomycin, a natural Saccharomyces cerevisiae biocide, on Hanseniaspora guilliermondii cells surfacePublication . Calvário, Joana; Silva, Nelly; Almeida, M. Gabriela; Albergaria, Helena; Eaton, Peter; Macedo, Anjos L.; Caldeira, JorgeABSTRACT: During spontaneous wine fermentations, most of the non-Saccharomyces yeasts present in grape musts show an early decline in their population. It was traditionally assumed that Saccharomyces cerevisiae (S.c.) prevalence was due to the higher resistance of this species to ethanol. However, wine fermentations performed with single cultures of non-Saccharomyces strains showed that those strains could withstand much higher ethanol levels [1]. It was then found that S.c. (strain CCMI 885) produced antimicrobial peptides (AMPs) that are responsible for the early death of the non Saccharomyces yeasts [2]. In previous work, we isolated, purified and sequenced those ntimicrobial peptides (AMPs) and found that they derive from the glyceraldehyde 3-phosphate dehydrogenase enzyme [3]. These GAPDH-derived AMPs compose the natural biocide secreted by S.c., which we named saccharomycin, and are effective against sensitive yeasts both in its natural/isolated and synthetic form.
- GeoERA´s contribution towards resilience in Europe’s raw materials supply chainsPublication . Wittenberg, Antje; De Oliveira, Daniel Pipa Soares; González, Javier; Flindt Jørgensen, Lisbeth; Held, TomThe well-being of society and the interdependencies of national economies depend heavily on reliably functioning supply chains as the COVID-19 pandemic proved this long-known statement in everyone's daily life. None of the supply chains can do without the mostly mineral raw materials. The United Nations sees raw materials as the key component for achieving all 17 Sustainable Development Goals (SDGs).
- Baterias de Ião-Lítio: Materiais, Componentes, Integração e DesafiosPublication . Nogueira, Carlos; Gano, António; Rangel, C. M.RESUMO: O armazenamento eletroquímico de energia, através de baterias, constitui uma das tecnologias fundamentais para o armazenamento de energia, tanto nas redes elétricas com elevada penetração de fontes renováveis, como na mobilidade elétrica, com perspetivas de crescimento exponencial, destacando-se ainda a sua contribuição decisiva nos sistemas de armazenamento estacionário em comunidades de energia. Dos variados sistemas de baterias existentes no mercado, as baterias de ião lítio (LIB’s - Lithium-ion Batteries) ocupam atualmente o papel mais relevante.
- Recovery of mining waste as source of raw material for the synthesis of tetrahedrite-tennantite materials [Resumo]Publication . Neves, Filipe; Esperto, Luís; Figueira, Isabel; Mascarenhas, João; Salgueiro, Rute; Silva, Teresa; Correia, J.B.; Carvalho, Patricia Almeida; De Oliveira, Daniel Pipa Soares
- Mechanochemical synthesis of tetrahedrite materials using mixtures of synthetic and ore samples collected in the Portuguese zone of the Iberian Pyrite BeltPublication . Neves, Filipe; Esperto, Luís; Figueira, Isabel; Mascarenhas, João; Salgueiro, Rute; Silva, Teresa; Correia, J.B.; Carvalho, Patricia Almeida; de Oliveira, Daniel Pipa SoaresABSTRACT: Considering that the synthesis of tetrahedrite-based materials usually uses high purity elements, the evaluation of the direct application of ore samples as raw materials for their synthesis is a pertinent issue. In the present study, multiphase synthetic tetrahedrite samples were mixed with tetrahedrite-tennantite ore samples (in weight ratios of 0.8/0.2, 0.5/0.5 and 0.2/0.8) to produce tetrahedrite-based materials by solid-state mechanochemical syn-thesis. The ore samples were obtained from the abandoned Barrig ̃ao mine dumps and from the Neves Corvo mine, both located in the Portuguese zone of the Iberian Pyrite Belt, whose main constituents were found to be As-rich tetrahedrite and tennantite-(Fe), respectively. Depending on the ore sample and on the mixture ratios, the displacement reactions occurring during the synthesis process gave rise to different phase transformation paths. For the ratios of 0.5/0.5 and 0.2/0.8, the mixtures with the Barrig ̃ao ore were found to consist of a single sulfide phase, tetrahedrite-tennantite-(Fe), plus quartz, while famatinite was also observed in the 0.8/0.2 mixture. Tetrahedrite-tennantite-(Fe) phase was the main constituent of all mixtures with the Neves Corvo ore, but in all of them other sulfide phases, famatinite-luzonite and pyrite, were also present in addition to quartz. Despite being dissimilar, these results are very promising and encouraging, by confirming the possible direct usage of ore samples and of dump material for the synthesis of tetrahedrite-based materials with all the potential environmental-economic gains that can be obtained.