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- Insights into rare earth elements and other critical raw materials from Castelo Branco massif alluvial deposits (Portugal)Publication . Salgueiro, Rute; Silva, Teresa; Martín-Méndez, I.; de Oliveira, Daniel Pipa Soares; Batista, Maria Joao; Inverno, CarlosABSTRACT: Actual and future demands for critical raw materials and strategic raw materials (CRM/SRM) justify the global search for their potential sources and the exploration approaches to reach them. This study discloses the characterization of rare earth elements (REE) and other CRM-bearing alluvial heavy minerals samples sourced from the late- to post-tectonic Variscan Castelo Branco Massif (Portugal). It also contributes to an understanding of REE, Th, and U anomalies from local and correspondent stream sediments identified in past geochemical surveys. The alluvial samples were subjected to semiquantitative analysis of their minerals under a binocular microscope and to chemical analysis through portable X-ray fluorescence. A varied mineralogical association and a geochemical fingerprint compatible with their main granitic source was identified, revealing several minerals that carry CRM, in which REE and titanium minerals stood out. The titanium minerals have the higher average abundance (54%), being ilmenite-dominant (50%), as supported by the relatively higher Ti content of these samples (up to 28.88%). The REE minerals occur as accessories and have a summing average of 12%, in which monazite is the most abundant (4.97%). Geochemical data support alluvial monazite as the mineral with the highest REE and Th concentrations, as described in the literature on its granitic source. In addition, the magnetic fraction of samples (∼85%) that includes monazite and xenotime presents LREE anomalous contents (up to 4,557 mg/kg) in relation to their granitic source, NASC, and even to ΣREE anomalous values revealed by local stream sediments. The Th (up to 1,969 mg/kg) and U (up to 244 mg/kg) contents follow the same trend. Nevertheless, the nonmagnetic mineral fraction that includes apatite and zircon reaches higher U contents (up to 448 mg/kg). This study indicates that the SRM Ti (ilmenite) and LREE (monazite) have the potential to form placer deposits sourced from Castelo Branco granitic rocks in a wider area, which is supported by the regional Ti placers exploited in the past. The occurrence of other accessory elements/minerals with industrial applicability associated with those placers may also represent future added value.
- Ranked Mappable Criteria for Magmatic Units: Systematization of the Ossa-Morena Zone Rift-Related Alkaline BodiesPublication . Roseiro, José; Moreira, Noel; de Oliveira, Daniel Pipa Soares; Silva, Marcelo; Eguiluz, Luis; Nogueira, PedroABSTRACT: The Ossa-Morena Zone (SW Iberian Massif) hosts the largest set of Cambro-Ordovician alkaline magmatic plutons related to the Palaeozoic rifting of the northern Gondwana margin so far described. An organized framework for their classification at different scales is proposed through data-driven ranks based on their distinctive petrological features relative to other rift-related magmatic rocks found throughout western Europe. The classification method aims to enhance geological mapping at different scales, regional- and continental-scale correlations, and, as such, facilitate the petrogenetic interpretation of this magmatism. The hierarchical scheme, from highest to lowest rank, is as follows: rank-1 (supersuite) assembles rocks that have distinctive characteristics from other magmatic units emplaced in the same magmatic event; rank-2 (suite) categorizes the units based on their major textural features, indicating if the body is plutonic, sub-volcanic, or a strongly deformed magmatic-derived unit; rank-3 (subsuite) clusters according to their spatial arrangement (magmatic centres) or association to larger structures (e.g., shear zones or alignments); rank-4, the fundamental mapping unit, characterizes the lithotype (alkaline granite, alkaline gabbro, syenite, albitite, etc.) by considering higher ranks (alkalinity and textural aspects); rank-5 characterizes the geometry of individual plutons (with several intrusions) or swarms; rank-6 (smallest mappable unit) corresponds to each intrusion or individual body from a swarm. Although this classification scheme is currently presented solely for the Ossa-Morena Zone, the scheme can be easily extended to incorporate other co-magmatic alkaline bodies, such as those in the NW Iberian allochthonous units or other peri-Gondwanan zones or massifs, in order to facilitate regional correlations of the rift-related magmatism.