RM - Artigos em revistas internacionais
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- Corrigendum to “Critical raw materials in the global high-throughput ceramic industry” [Sustainable Materials and Technologies 39 (2024) e00832]Publication . Garcia-Ten, Javier; Dondi, Michele; Lisboa, Jose; Cabedo, Monica Vicent; Perez-Villarejo, Luis; Rambaldi, Elisa; Zanelli, ChiaraABSTRACT: The authors regret that an error in the unit of the global output of boron occurred: the correct value is 4.13 million tons per year of borates, corresponding to 2.29 million tons B2O3 in 2018. Thus, the presumable consumption of borates by the ceramic industry (around 250,000 tons per year, B2O3 content) corresponds to 11 ± 1% of the global output of borates. In comparison, estimates from the mining industry (Orocobre 2019 Annual Report; EtiMaden 2022 Boron Report) place the borate demand for the production of ceramic frits at a share of 14%, corresponding to approximately 320,000 tons per year (B2O3 content).
- GEMAS: Boron as a geochemical proxy for weathering of European agricultural soilPublication . Négrel, Philippe; Ladenberger, Anna; Demetriades, Alecos; Reimann, Clemens; Birke, Manfred; Sadeghi, Martiya; The EuroGeoSurveys GEMAS Project TeamABSTRACT: bout a century ago, B was recognised as an essential element for the normal growth of plants and terrestrial organisms. Limitations for plant development have been recognised in agricultural systems, particularly in highly weathered soil. Boron is rarely analysed in whole rock or soil analysis, as it requires specific analytical techniques. It is often determined, after partial extraction (aqua regia or Ca-Cl), usually on a limited number of samples. Many more questions than answers exist about the environmental behaviour of B. We present B contents in agricultural soil samples (0-10 cm) collected in 33 European countries (5.6 million km2) during the GEMAS (GEochemical Mapping of Agricultural and grazing land Soil) continental-scale project. The B content, determined by ICP-MS following hot aqua regia extraction, varies in European agricultural soil from 0.5 to 49 mg/kg (median 2.42 mg/kg, n = 2108), which is somewhat similar to total B estimates for the Upper Continental Crust (17-47 mg/kg). Its spatial distribution in agricultural soil shows a patchy pattern with low values in regions with granitic bedrock and high contents in soil formed over limestone and in volcanic areas. Boron geochemical behaviour in soil is strongly dependent on other factors such as pH, CEC, presence of organic matter, clay and secondary oxides and hydroxides. Boron geochemical mapping at the continental scale in arable soil allows investigations of plant health, i.e., the beneficial and adverse effects due to the nutritional status of boron.
- Detrital zircon U-Pb geochronology of the Moatize and N’Cond´edzi coalfields, Zambezi Karoo Basin of Mozambique: Implications for provenance, sediment dispersal and basin evolutionPublication . Fernandes, Paulo; Jorge, Raul CG Santos; Albardeiro, Luís; Chew, David; Drakou, Foteini; Pereira, Zélia; Marques, JoãoABSTRACT: Detrital zircon U-Pb geochronology of the Moatize and N'Condedzi coalfields in the Zambezi Karoo Basin of Mozambique provides key insights into the regional provenance, sediment dispersal pathways and basin evolution. Borehole cores from the two coalfields reveal a stratigraphy spanning the early Roadian (middle Permian) to the Carnian (Upper Triassic). The Permian sandstones of the Moatize Coalfield (MC) yield three detrital zircon populations, with ages ranging from 1150 to 950 Ma, 900-780 Ma and 650-490 Ma. In contrast, the Permian sandstones of the N'Condedzi Coalfield (NC) have only one population, which ranges from 1150 to 950 Ma. During the Permian, the provenance area for the NC was the Tete-Chipata Terrane and Malawi Complex (1150-950 Ma) to the north-northeast. In the MC, the detrital zircon populations of the early lake delta depositional setting (Roadian to Wordian) indicate a main provenance in the Zambezi Belt (900-780 Ma) located to the south of the MC, with minor sourcing from the Nampula Block (1150-950 Ma and 650-490 Ma) to the east. The transition from a lake delta to an alluvial depositional setting is attributed to a major tectonic event in the MC, which involved the formation of a braided channel belt. Sandstones from this braided channel belt yield three detrital zircons populations (650-490 Ma, 900-780 Ma and 1150-950 Ma), indicating provenance from both the Zambezi Belt and the Nampula Block. The overlying sandstones in the MC show only a minor population from the Zambezi Belt (900-780 Ma), implying a shift in provenance to the Nampula Block that was likely induced by tectonics. The absence of detrital zircon populations of 900-780 Ma and 650-490 in the Permian sandstones of NC implies that the two coalfields were not connected during the mid to late Permian. It is likely that an intra-rift horst (the Mesoproterozoic Gabbro-Anorthosite Tete Suite) separated the two coalfields. The Lower Triassic sandstones of the NC yield a main detrital zircon population indicating provenance from the TeteChipata Terrane and Malawi Complex (1150-950 Ma). A minor population at 650-490 Ma is linked to increased aridity at the Permian - Triassic boundary, which caused expansion of the watershed across the Tete-Chipata Terrane and the Malawi Complex. The Upper Triassic sandstones in the NC yield a 1150-950 Ma detrital zircon population, indicating provenance from the Tete-Chipata Terrane and Malawi Complex and a return to the source-to-sink conditions seen in the mid to late Permian.
- Contact metamorphism and dolomitization overprint on Cambrian carbonates from the Ossa‑Morena Zone (SW Iberian Massif): implications to Sr‑chronology of carbonate rocksPublication . Roseiro, José; Moreira, Noel; Andrade, Laura; Nogueira, Pedro; de Oliveira, Daniel Pipa Soares; Eguiluz, Luis; Mirao, Jose; Moita, Patrícia; Santos, José Francisco; Ribeiro, Sara; Pedro, J.ABSTRACT: he Cambrian Series 2 Carbonate Formation from the Alter do Chão Elvas-Cumbres Mayores unit (Ossa-Morena Zone, SW Iberian Massif) is composed of regionally metamorphosed marbles and marlstones that underwent chlorite zone metamorphism and preserve the primaeval limestone 87Sr/86Sr ratios (0.7083–0.7088). These are consistent with the established Lower Cambrian seawater curve, and therefore used for age constraints in formations lacking fossil contents. The regional mineralogical and Sr-isotopic features of the carbonate rocks are frequently overprinted by the effects of contact metamorphism induced by magmatic bodies emplaced during rift-related and synorogenic events of the Palaeozoic, as well as by post-metamorphic dolomitization processes. The development of calc-silicate minerals due to contact metamorphism is common in the rocks of the Carbonate Formation and apparently results from the interaction of the protolith with fluids of different origin: (i) internally produced fluids released by conductive heating (observed in external contact aureoles) and (ii) external intrusion-expelled fluids that, besides leading to the appearance of distinctive assemblages, also promote an influx of strontium content (observed in roof pendants). Calc-silicate mineralogy varies substantially throughout the region, likely due to the heterogeneous distribution of silicate minerals of the protolith, progression of intrusion-driven fluids, and the irregular effect of thermal gradients. Results suggest that high-grade contact metamorphism (hornblende facies or higher) and dolomitization processes imposed on the Carbonate Formation significantly influence the isotopic signatures of the carbonates, providing limitations in applying Sr-isotopic chronology.
- A Geological Service for Europe: building trust through interdisciplinary and intersectoral collaborationPublication . Hollis, Julie; Calcagno, Philippe; Bertrand, Guillaume; de Oliveira, Daniel Pipa Soares; Negrel, Philippe; Díaz-Martínez, Enrique; La Vigna, Francesco; Poyiadji, Eleftheria; Tonné, Nathalie; Van Heteren, Sytze; Dakin, Nicola; Hinsby, Klaus; Van Der Keur, Peter; Siddiqi, Gunter; Čápová, Dana; Pizzocolo, FrancescoABSTRACT: Geology encompasses all of the Earth sciences and thus is multidisciplinary. It does not respect geopolitical borders, so requires teamwork across disciplines and between nations. Applying geological solutions to climate change increasingly requires transdisciplinary teamwork. This extends well beyond the geosciences to inform on issues of universal concern, e.g., deployment of renewable energy, management of groundwater resources, mitigation of climate-induced geohazards, and more. To achieve sustainability and success in these fields, it is essential to employ knowledge of subsurface, land, and subsea geology for the discovery, tracking, preservation, regulation, and exploitation of resources. This knowledge also supports integrated and coherent surface and subsurface spatial planning and the creation of cohesive laws guided by scientific insights. This in turn requires multi-stakeholder collaboration between scientific and governmental agencies, industry, and civil society, from research design to data and knowledge application. Such a broad spectrum of engagement is at the heart of the concept of a Geological Service for Europe, founded on a long history of collaboration between the Geological Surveys of Europe –extending networks, fostering innovation, sharing knowledge, building capacity and common standards. Given the current lack of public knowledge and negative perceptions of geology, collaborative efforts based on objective science can have a significant impact on building trust. This contribution highlights the collaboration of the Geological Surveys of Europe with non-geoscientific partners in serving society, supporting nature, and delivering the Green Deal.
- New pollen taxon Syncolpraedapollis angolensis nov. gen. sp. nov.: A noteworthy discovery reported in the preliminary investigation of the latest Eocene-latest Oligocene deposits in the Kwanza Basin, AngolaPublication . Mendes, Márcia; Pereira, Zélia; Rodrigues, Cristina F.A.; Nsungani, Nsungani, P.C.ABSTRACT: A palynostratigraphic study of the upper Cunga and lower Quifangondo deposits in the Cabo de São Brás section, Kwanza Basin, Angola, has revealed a new pollen named Syncolpraedapollis angolensis nov. gen. sp. nov. This finding was part of a wider survey in the upper Cunga and lower Quifangondo deposits of the Cabo de São Brás section, Kwanza Basin, Angola, covering the latest Eocene to the latest Oligocene. The novel pollen features unique characteristics, notably a 3-syncolporate structure with well-defined and distinctive pores. The pollen grain is adorned with a free but irregular reticulum with an irregular polygonal mesh. Syncolpraedapollis angolensis nov. gen. sp. nov. is sporadically but consistently observed within the latest Eocene-latest Oligocene interval, conspicuously absent in the underlying Eocene sediments (lower Cunga Formation) and occurring infrequently in the latest Oligocene sediments (lower Quifangondo Formation). Thus, it is plausible to infer a limited age range, likely restricted to the latest Eocene-latest Oligocene, as previous studies in the Kwanza Basin have not documented this pollen.
- Mapping and understanding Earth: Open access to digital geoscience data and knowledge supports societal needs and UN sustainable development goalsPublication . Hinsby, Klaus; Négrel, Philippe; de Oliveira, Daniel Pipa Soares; Barros, Renata; Venvik, Guri; Ladenberger, Anna; Griffioen, Jasper; Piessens, Kris; Calcagno, Philippe; Götzl, Gregor; Broers, Hans Peter; Gourcy, Laurence; van Heteren, Sytze; Hollis, Julie; Poyiadji, Eleftheria; Čápová, Dana; Tulstrup, JørgenABSTRACT: Open access to harmonised digital data describing Earth’s surface and subsurface holds immense value for society. This paper highlights the significance of open access to digital geoscience data ranging from the shallow topsoil or seabed to depths of 5 km. Such data play a pivotal role in facilitating endeavours such as renewable geoenergy solutions, resilient urban planning, supply of critical raw materials, assessment and protection of water resources, mitigation of floods and droughts, identification of suitable locations for carbon capture and storage, development of offshore wind farms, disaster risk reduction, and conservation of ecosystems and biodiversity. EuroGeoSurveys, the Geological Surveys of Europe, have worked diligently for over a decade to ensure open access to harmonised digital European geoscience data and knowledge through the European Geological Data Infrastructure (EGDI). EGDI acts as a data and information resource for providing wide-ranging geoscience data and research, as this paper demonstrates through selected research data and information on four vital natural resources: geoenergy, critical raw materials, water, and soils. Importantly, it incorporates near real-time remote and in-situ monitoring data, thus constituting an invaluable up-to-date database that facilitates informed decision-making, policy implementation, sustainable resource management, the green transition, achieving UN Sustainable Development Goals (SDGs), and the envisioned future of digital twins in Earth sciences. EGDI and its thematic map viewer are tailored, continuously enhanced, and developed in collaboration with all relevant researchers and stakeholders. Its primary objective is to address societal needs by providing data for sustainable, secure, and integrated management of surface and subsurface resources, effectively establishing a geological service for Europe. We argue that open access to surface and subsurface geoscience data is crucial for an efficient green transition to a net-zero society, enabling integrated and coherent surface and subsurface spatial planning.
- Characterization of Tableware from Fábrica de Loiça de Sacavém : Linking Analytical and Documental ResearchPublication . Coutinho, ML; Veiga, JP; Ruivo, Andreia; Silva, Teresa; Bottura Scardina, Silvia; Lima, M.M.R.A.; Pereira, Carlos; Dias, Ana Carvalho; Dias, Luis; Vandenabeele, Peter; Roseiro, J. CarlosABSTRACT: Fabrica de Loica de Sacavem (ca. 1858-1994) was among the first to produce white earthenware in Portugal, becoming one of the country's leading ceramic manufacturers during the late 19th to early 20th centuries. Research on white earthenware has accompanied the growing interest in post-industrial archaeology but is still poorly explored compared to more ancient ceramic productions. This study focused on the ceramic body, glazes, and colourants of tableware produced by Fabrica de Loica de Sacavem during the first 50 years of its activity (1859-1910). A multi-analytical approach was selected to investigate the chemical and mineralogical composition of the ceramic body, glaze, and pigments using optical microscopy, variable-pressure scanning electron microscope energy-dispersive X-ray spectroscopy (VP-SEM-EDS), mu-Raman spectroscopy, mu-X-ray Diffraction (mu-XRD), and reflectance spectroscopy (hyperspectral image analysis). The studied tableware was produced with a Ca-poor siliceous-aluminous white earthenware ceramic body covered with transparent alkali lead or lead borosilicate glaze, and most colourants were complex Cr-based pigments. These results are in agreement with the little documental evidence from this period found in the manufacturer's archives.
- Unlocking the Secondary Critical Raw Material Potential of Historical Mine Sites, Lousal Mine, Southern PortugalPublication . de Oliveira, Daniel Pipa Soares; Gonçalves, Pedro; Morais, Igor; Silva, Teresa; Matos, João Xavier; Albardeiro, Luís; Filipe, Augusto; Batista, Maria Joao; Santos, Sara; Fernandes, JoãoABSTRACT: A steady supply of mineral raw materials is vital for the transition to a low-carbon, circular economy. The number of active mines in Europe has severely declined over the last century and half, giving rise to many abandoned mining waste sites and corresponding geological heritage. Also, the rise in minerals demand for large-scale deployment of renewable energy requires the continued and steady availability of key minerals. The supply risk associated with unpredicted geopolitical events needs to be eliminated/mitigated. Historical mine waste sites are the answer but evaluating mine waste is a lengthy and costly exercise. The study, undertaken in the Lousal Mine, used small unmanned aerial systems (sUASs) to model and determine mine waste volumes by generating orthomosaic maps with quick, inexpensive, and reliable results. Calculated mine waste volumes between 308,478 m3 and 322,455 m3 were obtained. XRD and p-XRF techniques determined the mineralogy and chemistry of waste, which varied from mineralization and host rocks with hydrothermal alteration and numerous neogenic sulphates (mostly gypsum, rhomboclase, ferricopiapite, coquimbite, and jarosite) related with supergene processes and weathering. The study shows the viability of using these sUASs to successfully model historical mine waste sites in an initial phase and for future monitoring programs.
- Historical lime-based flooring mortars from the Church of Santa Maria de Alcobaça monastery (12th century), Portugal: A multi-analytical approachPublication . Carvalho, Fernanda; Nunes, A.; Pagará, A.; Costeira, I.; Silva, Teresa; Lima, M.M.R.A.; Veiga, JPABSTRACT: The Monastery of Alcobaça houses in reserve the ceramic tiles that adorned the floor of the church's apse. These tiles were removed during rehabilitation works and many preserve part of their original fixing mortars. A comprehensive analysis of 21 samples was conducted using a multi-analytical approach (X-ray fluorescence, X-ray diffraction, scanning electron microscopy–energy-dispersive X-ray spectroscopy, μ-Raman spectroscopy, thermogravimetry–differential thermal analysis, optical microscopy, and colorimetry). Results suggest compositional variations in the samples from the back and sides of the ceramic tiles; however, the mineralogy and general characteristics of the aggregates remained consistent between the samples and are coherent with the local geology, suggesting a shared historical origin.