ME - Resumos em livros de actas
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- Enhancing Corrosion Resistance of Al-Mg Alloys through Biomineralization [Resumo]Publication . Marques, Maria João; Fori, Benoit; Mercier, Dimitri; Seyeux, Antoine; Zanna, Sandrine; Marcus, Philippe; BASSEGUY, RegineABSTRACT: In recent decades, new emerging microbiological technologies have been studied, based on the recognition that microorganisms can inhibit corrosion by different mechanisms, the so-called MICI (microbiologically influenced corrosion inhibition), opening up different lines of research. In this context, biomineralization has been attracting the attention of researchers, with an increasing number of studies showing that different types of mineralized layers formed on metal surfaces can reduce the risk of corrosion.
- Enhancing Proton Conductivity of SPEEK Based Membranes by Incorporation Graphene Oxide / Bisphosphonic acid dopant [Resumo]Publication . Teixeira, Fatima; Teixeira, António Paulo Silva; Rangel, Carmen M.ABSTRACT: The most commercially successful membrane for applications in fuel cell and electrolyzers, perfluorinated sulfonic NafionR, exhibits relevant performance limitations due to its dependence on water content with consequent proton mobility restrictions, environmental concerns and very high cost. Poly(etheretherketone) (SPEEK) polymer appears as a versatile non-fluorinated alternative for a low-cost and a more environmentally friendly membrane. Our previous studies showed that the incorporation of biphosphonic acid dopants (BPs) into the mentioned polymeric matrices, improves membrane proton conduction and durability1-5. In this work, we prepared and evaluated new doped SPEEK membranes using graphene oxide (GO) with bisphosphonic acid functionalities as dopant (GOBP), anticipating superior membranes properties, including proton conductivity.
- Green Catalytic Transformation of CO₂ to Syngas Using Aerogels [Resumo]Publication . Paninho, A. B.; Messias, Sofia; Fernandes, I.; Rangel, Carmen M.; Nunes, A. V. M.; Branco, Luis; Martins, Rodrigo; Mendes, Manuel Joao; Machado, Ana
- New membranes for CO2 electrochemical reduction {Resumo]Publication . Teixeira, Fatima; Teixeira, António Paulo Silva; Messias, Sofia; Martins, Rodrigo; Mendes, Manuel Joao; Machado, Ana; Rangel, Carmen M.
- New SPEEK Membranes Modified with Bisphophonate Dopants [Resumo]Publication . Teixeira, Fatima; Teixeira, António Paulo Silva; Rangel, Carmen M.ABSTRACT: ustainable emerging energy technologies are pivotal to a decarbonized society that still continuously increases its energy demands. Fuel cells and eletrolyzers are part of these promising sustainable technologies, but they still depend on several factors, especially on their membranes. These are a key component acting as a separator, between their different materials and electrolytes of different devices' compartments, and as a selective ion-exchange barrier, controlling the ion flow and species permeability. Sulfonated poly(etheretherketone) (SPEEK) polymer is a versatile non-fluorinated alternative, as a low-cost and more environmentally friendly membrane, to the most commercially successful membrane based on the perfluorinated sulfonic Nafion®. Also, our previous studies showed that the incorporation of BPs dopants into the polymeric matrices, modifies the properties of the doped membranes, including their proton conduction and durability.
- Solar Electrochemical CO2 Reduction to Syngas [Resumo]Publication . Messias, Sofia; Paninho, A. B.; Nunes, Daniela; Rangel, Carmen M.; Nunes, A. V. M.; Branco, Luis; Martins, Rodrigo; Mendes, Manuel Joao; Machado, Ana