CTM - Artigos em revistas internacionais
URI permanente para esta coleção:
Navegar
Entradas recentes
- Noise-Induced fatigue in maritime work environments: A cross-sectional study of occupational exposure among seafaring personnel in IndonesiaPublication . Febriyanto, Kresna; Mourão, Luis; Matos, Maria Luísa; Guedes, JoanaABSTRACT: Objective: The study aims to examine the relationship between occupational noise exposure and the levels of physical, mental, and emotional fatigue among speedboat crew members.Methods: A cross-sectional study was conducted among speedboat crew members in Tarakan, North Kalimantan, Indonesia on November 2024. This study involves two categories of ship personnel as samples, namely, crew members and captains were 87 crews were enrolled in this study. We calculated using Spearman's rho models to analysed the data.Results: The study found that occupational noise levels on speedboats ranged from 77.9 to 100.9 dB(A), with one vessel exceeding the safe exposure threshold. The level of fatigue among the respondents is mostly in the low category (69% - 74.7%). Occupational noise aboard speedboats is a significant contributor to physical (r = .715, p = .040) and mental fatigue (r = .839, p = .022).Conclusion: The results of the statistical test indicate that, besides the main research variable, other confounding variables correlate with the fatigue levels of the crew, such as age, educational background, and working period. While overall fatigue levels were low, the study highlights the need to address noise exposure and other correlated factors to safeguard seafarers well-being.
- Mid-Neoproterozoic extensional tectonics in the Larsemann Hills, East Antarctica: Implications for Indo-Antarctic correlation in RodiniaPublication . Chatterjee, Sandro; Dev, J. Amal; Debnath, Aishi; Ghosh, Anuj; Dey, Soham; Mukherjee, Anik; Arora, Devsamridhi; Tomson, Joseph Kallukalam; Guimarães, Fernanda; Pant, Naresh Chandra; Gupta, SaibalABSTRACT: The supercontinents Rodinia and Gondwana are believed to have assembled through orogenic events at similar to 1000 Ma and similar to 550 Ma, respectively. The Larsemann Hills, part of the extended Rayner Complex of East Antarctica, is a Neoproterozoic granulite terrane that was a part of both supercontinents. The tectonic evolution of the terrane in the Rodinia to Gondwana interval remains uncertain. This study integrates new field, microstructural, metamorphic and geochronological information to unveil a previously undocumented mid-Neoproterozoic thermo-tectonic event in the Larsemann Hills. Granulite facies metamorphism (M-1), synchronous with the deformation, D-1, is interpreted to have occurred in the Larsemann Hills at similar to 1000 Ma, followed by a crustal shortening (D-2) event that continued from similar to 990-900 Ma, signifying the incorporation of the Rayner crustal unit into Rodinia. Subsequent mid-Neoproterozoic extensional deformation (D-3), characterized by NW-SE trending S-3 shear zones, reoriented pre-existing structural fabrics. The extensional deformation operated under amphibolite facies metamorphic conditions (M-2) and resulted in a post-peak decompressive P-T trajectory. UPb LA-ICPMS dates on zircons separated from metapelites within high D-3 strain zone yield clusters at similar to 700 Ma; zircons immediately adjacent to the shear zone yield ages around similar to 990-900 Ma. A thermal overprint at similar to 550 Ma is evident but weakly manifested in the western Larsemann Hills, with no unambiguously correlatable structural or metamorphic evidence, suggesting distance from the Gondwana orogenic front. The extensional deformation documented here is contemporaneous with extension in the northern Eastern Ghats Province, India that was contiguous with the Rayner Complex in the Neoproterozoic. This suggests that a major terrane-wide extensional event was associated with the disintegration of Rodinia. In the Neoproterozoic, the EGP-Rayner unit was therefore a tectonic entity distinct from cratonic India, with only the former being an integral component of Rodinia.
- Evaluation of occupational exposure to flour dust and additives in a milling industryPublication . Matos, Maria Luísa; Cardoso, Ricardo TeixeiraABSTRACT: This study aimed to assess an environmental risk in a workstation: the occupational exposure of workers to flour dust, and mixtures of flour dust with additives in the cereal milling industry. The purpose was to understand how exposure to flour dust, and mixtures of flour dust with additives affects the health of workers. In the facilities of the milling company where this study was carried out, there is an area where workers are particularly exposed to flour dust and mixtures of flour dust with additives involved. Therefore, one of the main objectives of this study was to evaluate if these workers were subjected to occupational health hazards during their working hours, due to the contact with suspended flour dust in their workstations, focusing special attention to this area, whenever possible. A sampling of particles suspended in the air was carried out, in order to perform a quantitative analysis. Suction pumps were used, placed on workers, who work in three different workstations, to make a quantitative comparison. An average concentration (a.c.) of 17.27 mg/m3 was obtained in the workstation of the preparation of mixtures, an a. c. of 1.35 mg/m3 and one of 2.25 mg/m3 in the bagging workstation – for plain flour and for added flour, respectively. It was found that all values obtained exceed the Exposure Limit Value proposed by the Standard NP 1796:2014, which presents a value calculated as a weighted average of 0.5 mg/m3. Mitigation with the use of personal protective equipment (PPE), FFP3 type masks, is enough to protect workers.
- Pre-Mesoproterozoic crustal framework and Mesoproterozoic evolution of the SW Angolan Shield: structural, geochemical, and isotopic insights from the Kunene Complex and surrounding basementPublication . Merino-Martínez, E.; Ferreira, Ezequiel; Valverde-Vaquero, Pablo; Rodrigues, José Feliciano; Escuder-Viruete, Javier; Garcia-Lobon, Jose Luis; Beranoaguirre, Aratz; Feria, María Carmen; Rey-Moral, Carmen; Silva, Paulo Bravo; González-Cuadra, Pablo; Sousa, João Carlo; Potti, Julián; Máximo, J.; Gutiérrez-Medina, M.; Gumiel, J.C.; Galán, Gustavo; Mochales, Tania; Manuel, José; Cordeiro, Domingos; Tassinari, Colombo C. G.; Montero, P.; Sato, Kei; Fuenlabrada, José Manuel; Galindo, CarmenABSTRACT: The southwestern Angolan Shield hosts the Earth's largest Mesoproterozoic massif-type anorthosite complex (up to 53,500 km(2)), the Kunene Complex (KC). This complex is the result of a long-lived (similar to 200 Ma) episodic emplacement of coalescent magmatic pulses. The recent acquisition of multidisciplinary data during the PLANAGEO project has significantly enhanced our understanding of the Precambrian crustal framework from the southwestern Angolan Shield. Combined multi-isotope, structural and geophysical data reveals distinctive crustal zones in the southwestern Angolan Shield that clearly influenced KC's emplacement within a back-arc setting. The spatio-temporal arrangement of KC pulses suggests westwards magma migration within a complex contractional regime involving large strike-slip systems. A long-lasting and extensive accretionary orogen was responsible for the tectono-thermal activity recorded during most of the Mesoproterozoic. Crustal thinning and partial melting of isotopically heterogeneous lower-crustal sources through mantle upwelling promoted the episodic felsic magmatism contemporaneous with the KC. Crustal contamination processes are evident in gabbroanorthosites, indicating mantle metasomatism and interaction with wall-rocks and granite melts during ascent, upwelled by lateral-driven forces. Deposition of extensive metasedimentary sequences (<1.26 Ga) covering the KC, along with 1.23-1.07 Ga sublithospheric and mantle-derived magmatism, indicate a shift from a compressional to an extensional regime during late-Mesoproterozoic times. Regional correlations with other Mesoproterozoic units in African and Brazilian counterparts suggest a shared geological evolution, despite potential differences in tectonic setting. These findings supports a refined geological model for the Mesoproterozoic evolution of the southwestern part of the Congo Craton.
- Zircon U-Pb and Lu-Hf isotopes reveal the crustal evolution of the SW Angolan Shield (Congo Craton)Publication . Ferreira, Ezequiel; Lehmann, Jeremie; Rodrigues, José Feliciano; Hayes, Ben; Merino-Martinez, Enrique; Milani, Lorenzo; Bybee, Grant M.; Smith, Trishya M. Owen; García-Lobón, J. L.; Tassinari, Colombo C. G.; Ueckermann, Henriette; Sato, Kei; Silva, Paulo Bravo; Correia, João; Labaredas, José; Duarte, Laurent; Molekwa, Mmasetena Anna; Manuel, José; Victorino, Américo da MataABSTRACT: The crustal evolution of the Angolan Shield (AS) remains poorly constrained. To address this, we analysed U-Pb and Lu-Hf isotopes in detrital and igneous zircons to investigate the age and provenance of extensive sedimentary strata in southwestern Angola and use it as a proxy to gain insight into the Archean to Mesoproterozoic evolution of the region. Mesoproterozoic maximum depositional ages for the Iona (<1323 +/- 13 Ma), Ompupa (<1215 +/- 13 Ma), and Cahama (<1184 +/- 23 Ma) siliciclastics challenge previous correlations with the Paleoproterozoic Chela Group. Provenance analysis reveals that the Mesoproterozoic strata were derived internally from the AS. Our combined dataset indicates that the widespread Eburnean magmatism (-2.05-1.93 Ga) resulted from reworking of Archean crust, possibly in collision orogens. A major increase in the eHf(i) and eNd(i) values at - 1.87-1.73 Ga indicates a change in geodynamics, with magmatism of the Epupa-Namibe Metamorphic Complex (ENMC) generated in an extensional accretionary orogen at the southern margin of the Eburnean-Archean crustal block. Magmatism resumed in the Mesoproterozoic (-1.56-1.50 Ga), with suprachondritic eHf(i) values indicating significant juvenile addition. The Kunene Complex (KC: -1.50-1.36 Ga) anorthosite-mangerite-charnockite-granite magmatism displays variable eHf(i) and eNd(i) values, consistent with mixing between reworked ENMC-crust and juvenile melts in a long-lived accretionary orogen back-arc region. Post-KC (-1.36-1.30 Ga) magmatism shows an increased juvenile contribution, potentially linked to partial melting of ENMC and - 1.56-1.50 Ga juvenile crust during an orogenic event, or alternatively, related to renewed slab retreat and back-arc extension. The Hf isotopic compositions of - 1.29-1.18 Ga zircons are compatible with a renewed input from the depleted mantle and/or reworking of the earlier - 1.56-1.50 Ga juvenile crust. Emplacement of - 1.13-1.10 Ga mafic dikes/sills marks the end of Mesoproterozoic magmatism in the AS. Our new data enhance our understanding of the Archean to Mesoproterozoic crustal evolution of the AS.
- The paleoenvironmental and thermal histories of the Permian Irati formation shale in the paraná basin, Brazil: An integrated approach based on mineralogical and organic imprintsPublication . Rocha, Rocha, H.V.; Sant'Anna, L.G.; Rodrigues, Cristina F.A.; Mendes, Márcia; Pereira, Zélia; Lopes, Gilda; Fernandes, Paulo; Pereira, Egberto; Tassinari, Colombo C. G.; Sousa, M.J. Lemos deABSTRACT: Mineralogical assemblages and organofacies are important sources of information to recover the paleoenvironmental and thermal histories of shale deposits. In this study, a detailed qualitative and quantitative characterization of the Permian Irati Formation (Assistência Member) shale is based on mineralogical (XRD and SEM-EDS) and organic components (TOC, Rock-Eval pyrolysis, organofacies, TAI, fluorescence and vitrinite reflectance measurements) and provides integrated data about sediment provenance, depositional environment, diagenesis, and thermal history, while supporting interpretations on the Paraná Basin (PB), Brazil, paleogeography and its correlation to the southwest Gondwana. The results revealed a prevailing type I/II kerogen, with type III kerogen being also present but mainly confined along the paleoshoreline of the PB. The dominance of fluorescent amorphous organic matter (AOM) combined with framboidal pyrite suggests microbial activity in an anoxic-dysoxic neritic-marine paleoenvironment. Additionally, common to abundant well-preserved phytoclasts, as well as the occurrence of Botryococcus braunii, indicates freshwater influx in a brackish marine depositional setting. Immature to early-oil window thermal maturities prevail across the PB, according to the organic maturation indicators. The combined analysis between the organic matter evolution with clay mineralogy, such as the occurrence of interstratified clays (e.g., I/S) and its positive correlation with depth suggest that burial diagenesis reached the transition to early catagenesis on the north, southeast, and south of the basin, attributing a shale oil potential for the Irati Formation on a regional scale. Local scale imprints of the Early Cretaceous Paraná-Etendeka Large Igneous Province (LIP), and its thermal effect in the Irati Formation shale components, are recorded as clay authigenesis (e.g., smectite webby texture and clay coating development), crystallization of minerals by low to high-grade of thermal alteration (e.g., corrensite, talc, lizardite and diopside), and by local scale gas-window maturities. Such thermal alteration, identified in the proximity to intruded sills and dykes, led to a heterogeneous organic maturation pattern with implications on shale gas and shale oil potential of the Irati Formation shale, demonstrating that these subjects in the Paraná Basin should be assessed locally.
- The upper Hauterivian Barremian (Lower Cretaceous) Arrifes section (Algarve Basin, Southern Portugal): a palynostratigraphic and palaeoenvironmental approachPublication . Mendes, Márcia; Descamps, G.S.; Fernandes, Paulo; Lopes, Gilda; Jorge, Raul CG Santos; Pereira, ZéliaABSTRACT: Integrated sedimentological, palynological, and palynofacies analyses of the Arrifes section in the central Algarve Basin (southern Portugal) provided new information on the age and environments of this Lower Cretaceous sequence. The sedimentary succession at the Arrifes section consists of fossiliferous interbedded limestones, marly limestones, and marls, dated as latest Hauterivian to late Barremian age (Lower Cretaceous) based on key dinoflagellate taxa. During this interval, the Arrifes area records climatic shifts and, multiple sea-level fluctuations; overall deposition was in shallow subtidal to intertidal settings, with deposition of carbonate and marly sediments. During the latest Hauterivian to earliest Barremian interval, an evident sea-level fall culminated in the subaerial exposure of the local carbonate ramp with increased influx of clastic sediments. However, during the Barremian, both sedimentological and palynological analyses suggest an overall deepening of the water depth towards the top of the section. These overall increase in the water column are confirmed by oscillation of terrestrial/marine palynomorph groups and supported by dinosaur track levels at the top of the succession; the latter indicate that sedimentation occurred in intertidal to subtidal environments. Finally, an attempt was made to correlate the Arrifes section with other sections from the Algarve Basin, as well as with broader region. These new data suggest a setting in the Tethyan basin influenced during the latest Hauterivian to the end of the Barremian. These new data allow local correlations and new palynological ages and paleoenvironmental interpretations for the Lower Cretaceous succession of the Algarve Basin.
- Separation of lepidolite from hard-rock pegmatite ore via dry processing and flotationPublication . Filippov, Lev O.; Filippova, Inna V.; Crumiere, Gabriel; Sousa, Rui; Machado Leite, Mário; Sousa, Ana Botelho de; Korbel, Chloe; Tripathy, Sunil KumarABSTRACT: A mineralogical study of Goncalo lithium-bearing mica-rich pegmatite ore (Portugal) indicated that lepidolite occurs in coarse-grained textures, which allows an appreciable liberation of gangue minerals (quartz, k-feldspar, and albite) from lepidolite. However, the intergrowth of these gangue minerals results in uncomplicated liberation (i.e., inclusions). Taking advantage of this coarse gangue liberation, optical ore sorting through image analysis was attempted in order to predict the grades of different-sized fractions using a random comminution algorithm. The ore-sorting process allowed the production of a marketable Li pre-concentrate product for metallurgy. Moreover, this method also highlighted the possible valuation of the reject as low-Li-content quartz-feldspar mixtures for the ceramic industry (reduction in the temperature of porosity closing). Furthermore, a scaled approach of grinding and sieving allowed the formation of a lepidolite-rich fraction (>210 mu m), which was processed using an electrostatic separator by varying key process parameters. The lepidolite and muscovite were separated to obtain a Li pre-concentrate assaying 3.5 % Li2O from a feed grade containing 1.8 % Li2O. Nevertheless, according to the zeta-potential measurements, the flotation test performed with the finer-sized fraction (-210 + 63 mu m) showed that lepidolite flotation was optimised between pH 3 and 5. In this pH range, concentrates from the rougher stage assayed 4.2-4.5 % Li2O, corresponding to 87-95 % Li recovery. At pH > 5, the selectivity decreases, and SiO2 analysis suggests the flotation of quartz and other silicates rather than lepidolite. Feldspar/quartz flotation was also tested using lepidolite flotation rejects to promote the separation of feldspars from quartz and obtain products for ceramic applications.
- A systematic review of sustainable gold extraction from raw ores using alternative leaching reagentsPublication . Sousa, Rui; Regufe, Maria João; Fiúza, António; Machado Leite, Mário; Futuro, AuroraABSTRACT: Drawing on recent experimental and commercial developments, this review reappraises potential substitute leach reagents for cyanide in the gold mining sector. In addition to extraction, the application of these reagents in the gold processing, pre-treatment and gold purification stages is explored. The main objective here is to discuss how the gold extraction process can be more sustainable, with a view to developing more greener leaching reagents.
- A new approach to palynostratigraphy of the middle late Famennian Gafo Formation, southern sector of the Pulo do Lobo Domain, SW Iberia (Portugal and Spain)Publication . Mendes, Márcia; Pereira, Zélia; Vaz, Nuno; Díez-Montes, Alejandro; Matos, João Xavier; Albardeiro, Luís; Fernandes, Paulo; Jorge, Raul CG Santos; Chew, DavidABSTRACT: New palynological results from the Gafo Formation (southern sector of the Pulo do Lobo Domain, South Portuguese Zone) are integrated with recently studied sections and drillholes from the Portuguese and Spanish sectors. A total of 44 samples were studied, 27 of which were positive for palynomorph taxonomy. This research revealed well preserved palynological assemblages, including 73 spore species allocated to 28 genera, four acritarch genera, three prasinophyte algae genera plus common chitinozoan remains. Some additional forms were retained under open nomenclature. From this, the first complete age determination for the Gafo Formation in Portugal and Spain was achieved, indicating a middle Famennian (Grandispora gracilis–Grandispora famenensis, GF Biozone) to a late Famennian (Grandispora echinata, VH Biozone) age. A greywacke sample from the same Gafo Formation was dated by U–Pb zircon geochronology and a maximum depositional age of 369 ± 2.5 Ma was obtained. A correlation between these palynological and U–Pb zircon data and the palynoflora assemblages of previous authors was made, as well as with the ages of felsic volcanic rocks found intercalated in the Gafo Formation, confirming the complex stratigraphy of Pulo do Lobo Domain. The results are consistent with stratigraphic mapping and structural interpretations, allowing a middle–late Famennian age (GF and VH Biozone) to be assigned to the Gafo Formation sedimentary rocks. This work has also contributed to a reinterpretation of Gafo Formation depositional facies correlatives (e.g. the Santa Barbara Group in Spain) as being the same lithological unit.