Publication
Asymmetric synthesis of secondary benzylic alcohols via arene chromium tricarbonyl complexes
| dc.contributor.author | Costa, M. Rute G. da | |
| dc.contributor.author | Curto, Maria João Marcelo | |
| dc.contributor.author | Davies, Stephen G. | |
| dc.contributor.author | Teixeira, Fatima | |
| dc.contributor.author | Thomson, James E. | |
| dc.date.accessioned | 2019-01-29T17:53:33Z | |
| dc.date.available | 2019-01-29T17:53:33Z | |
| dc.date.issued | 2018 | |
| dc.description.abstract | ABSTRACT: The use of O-methyl-N-(alpha-methylbenzyl)hydroxylamine as a novel chiral auxiliary in asymmetric ortho-deprotonation of the (eta(6)-arene) chromium tricarbonyl complexes is described. Upon quenching of the resultant ortho-lithiated complex with an electrophile, 1,2-disubstituted (eta(6)-arene) chromium tricarbonyl complexes were obtained in good yield and excellent levels of diastereoselectivity. | pt_PT |
| dc.description.version | info:eu-repo/semantics/publishedVersion | pt_PT |
| dc.identifier.citation | Costa, M. Rute G. da; Curto, M. João M.; Davies, Stephen G... [et.al.] - Asymmetric synthesis of secondary benzylic alcohols via arene chromium tricarbonyl complexes. In: Tetrahedron, 2018, Vol. 74, p. 5965-5973 | pt_PT |
| dc.identifier.issn | 0040-4020 | |
| dc.identifier.uri | http://hdl.handle.net/10400.9/3117 | |
| dc.language.iso | eng | pt_PT |
| dc.peerreviewed | yes | pt_PT |
| dc.publisher | Elsevier | pt_PT |
| dc.relation | Praxis XXI BD/5433/95 | pt_PT |
| dc.relation.publisherversion | https://doi.org/10.1016/j.tet.2018.08.033 | pt_PT |
| dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | pt_PT |
| dc.subject | Asymmetric synthesis | pt_PT |
| dc.subject | Hydroxylamines | pt_PT |
| dc.subject | Catalysis | pt_PT |
| dc.subject | Organic chemistry | pt_PT |
| dc.title | Asymmetric synthesis of secondary benzylic alcohols via arene chromium tricarbonyl complexes | pt_PT |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| oaire.citation.endPage | 5973 | pt_PT |
| oaire.citation.startPage | 5965 | pt_PT |
| oaire.citation.title | Tetrahedron | pt_PT |
| oaire.citation.volume | 74 | pt_PT |
| person.familyName | Teixeira | |
| person.givenName | Fatima | |
| person.identifier.ciencia-id | C014-509B-D1DC | |
| person.identifier.orcid | 0000-0003-0801-2068 | |
| person.identifier.scopus-author-id | 7102746385 | |
| rcaap.rights | openAccess | pt_PT |
| rcaap.type | article | pt_PT |
| relation.isAuthorOfPublication | 3daa40f1-7bb6-488d-83d9-04a61c655d67 | |
| relation.isAuthorOfPublication.latestForDiscovery | 3daa40f1-7bb6-488d-83d9-04a61c655d67 |