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- Analysis of the geological control on the spatial distribution of potentially toxic concentrations of As and F- in groundwater on a Pan-European scalePublication . Giménez-Forcada, Elena; Luque-Espinar, J. A.; López-Bahut, T.; Grima-Olmedo, Juan; Jiménez-Sánchez, Jorge; Ontiveros-Beltranena, Carlos; Elster, Daniel; Skopljak, Ferid; Voutchkova, Denitza; Hansen, B.; Hinsby, Klaus; Schullehner, Jörg; Malcuit, Eline; Gourcy, Laurence; Szőcs, Teodóra; Gál, Nóra; Porbjörnsson, Daði; Tedd, Katie; Borozdins, Dāvis; Rosenqvist, Lars; Debattista, Henry; Felter, Agnieszka; Cabalska, Jolanta; Mikołajczyk, Anna; Pereira, Ana Paula Teixeira; Sampaio, José; Perşa, Diana; Pantic, Tanja Petrović; Rman, Nina; Arnó, Georgina; Herms, Ignasi; Rosenqvist, LarsABSTRACT: The distribution of the high concentrations of arsenic (As) and fluoride (F-) in groundwater on a Pan-European scale could be explained by the geological European context (lithology and structural faults). To test this hypothesis, seventeen countries and eighteen geological survey organizations (GSOs) have participated in the dataset. The methodology has used the HydroGeoToxicity (HGT) and the Baseline Concentration (BLC) index. The results prove that most of the waters considered in this study are in good conditions for drinking water consumption, in terms of As and/or F- content. A low proportion of the analysed samples present HGT≥ 1 levels (4% and 7% for As and F-, respectively). The spatial distribution of the highest As and/or F- concentrations (via BLC values) has been analysed using GIS tools. The highest values are identified associated with fissured hard rock outcrops (crystalline rocks) or Cenozoic sedimentary zones, where basement fractures seems to have an obvious control on the distribution of maximum concentrations of these elements in groundwaters.
- Assessing Thermal Maturity through a Multi-Proxy Approach: A Case Study from the Permian Faraghan Formation (Zagros Basin, Southwest Iran)Publication . Spina, Amália; Cirilli, Simonetta; Sorci, Andrea; Schito, Andrea; Clayton, Geoff; Corrado, Sveva; Fernandes, Paulo; Galasso, Francesca; Montesi, Giovanni; Pereira, Zélia; Rashidi, Mehrab; Rettori, RobertoABSTRACT: This study focuses on the thermal maturity of Permian deposits from the Zagros Basin, Southwest Iran, employing both optical methods (Thermal Alteration Index, Palynomorph Darkness Index, Vitrinite Reflectance, UV Fluorescence) and geochemical analyses of organic matter (Rock Eval Pyrolysis and MicroRaman spectroscopy) applied to the Faraghan Formation along two investigated Darreh Yas and Kuh e Faraghan surface sections. Furthermore, an integrated palynofacies and lithofacies analysis was carried out in order to integrate the few studies on the depositional environment. The Faraghan Formation, which is widely distributed in the Zagros area, generally consists of shale intercalated with sandstones and pebble conglomerates in the lower part, followed by a succession of sandstone, siltstone and shaly intercalations and with carbonate levels at the top. The integrated palynofacies and lithofacies data confirm a coastal depositional setting evolving upwards to a shallow marine carbonate environment upwards. Rock Eval Pyrolysis and Vitrinite Reflectance analysis showed that the organic matter from samples of the Darreh Yas and Kuh e Faraghan sections fall in the mature to postmature range with respect to the oil to gas generation window, restricting the thermal maturity range proposed by previous authors. Similar results were obtained with MicroRaman spectroscopy and optical analysis such as Thermal Alteration Index and UV Fluorescence. Palynomorph Darkness Index values were compared with Rock Eval Pyrolysis and vitrinite reflectance values and discussed for the first time in the late stage of oil generation.
- Assessment of metal and metalloid contamination in soils trough compositional data: the old Mortórios uranium mine area, central PortugalPublication . Neiva, A.M.R.; Albuquerque, M.T.D.; Antunes, I. Margarida H. Ribeiro; Carvalho, P.C.S.; Santos, A. C. T.; Boente, C.; Cunha, Pedro Proença e; Henriques, S.B.A.; Pato, R. L.ABSTRACT: Soils from the old Mortórios uranium mine area were studied to look for contamination, as they are close to two villages, up to 3 km away, and used for agriculture. They are mainly contaminated in U and As and constitute an ecological threat. This study attempts to outline the degree to which soils have been affected by the old mining activities through the computation of significant hot clusters, Traditional geostatistical approaches commonly use raw data (concentrations) accepting that the analyzed elements represent the soil’s entirety. However, in geochemical studies these elements are just a fraction of the total soil composition. Thus, considering compositional data is pivotal. The spatial characterization, considering raw and compositional data together, allowed a broad discussion about not only the concentrations’ spatial distribution, but also a better understanding on the possibility of trends of “relative enrichment” and, furthermore an insight in U and As fate. The highest proportions (compositional data) on U (up to 33%), As (up to 35%) and Th (up to 13%) are reached in the south-southeast segment. However, the highest concentrations (raw data) occur in north and northwest of the studied area, pointing out to a “relative enrichment” toward the south-southeast zone. The Mondego Sul area is mainly contaminated in U and As, but also in Co, Cu, Pb and Sb. The Mortórios area is less contaminated than the Mondego Sul area.
- Assessment of metal and metalloid contamination in the waters and stream sediments around the abandoned uranium mine area from Mortórios, central PortugalPublication . Neiva, A.M.R.; Carvalho, P.C.S.; Antunes, I. Margarida H. Ribeiro; Albuquerque, M.T.D.; Santos, A.C.S.; Cunha, Pedro Proença e; Henriques, S.B.A.ABSTRACT: In the abandoned Mortórios uranium mine area there are quartz veins containing wolframite and sulphides and basic rock dykes with torbernite and autunite cutting a porphyritic granite. The basic rock dykes were exploited and produced about 27 t of U3O8, from 1982 to 1988. There are an open pit lake and nine dumps. Surface water and groundwater are contaminated in U, As, Cd, Cr, Cu, Fe, Mn, Ni and Pb. Stream sediments are contaminated in U, As, Th and W, which are adsorbed by smectite, kaolinite and iron- and aluminium- oxy-hydroxides. The maximum U concentrations are of 1268 μg/L in the open pit lake, 100 μg/L in surface water, 103 μg/L in groundwater and 81.5 mg/kg in stream sediments all downstream of the open pit lake and dumps. Further downstream the U concentration in water decreases, due to the high mobility of U (VI), but the U concentration in stream sediments increases. Calcium uranyl carbonate dominates in the open pit lake, but uranyl carbonate complexes dominate in surface water and gr oundwater. The maximum As concentrations are 56.0 μg/L in the open pit lake, 63.4 μg/L in the surface water and 66.7 μg/L in the groundwater, both downstream of the open pit lake and dumps. The arsenic occurs as As (V). The Mortórios area is compared with two other areas exploited from open pits, all located in the uranium-bearing Beira area of central Portugal. Vale de Abrutiga produced 90 t of U3O8 between 1982 and 1989 and Mondego Sul produced 75 t of U3O8 from 1987 to 1991. The two mines consist of quartz veins containing sulphides, saleeite and meta-saleeite at Vale de Abrutiga and with sulphides, autunite, torbernite, meta-uranocircite and meta-saleeite at Mondego Sul cutting the Schist-graywacke Complex. The mine area of Vale de Abrutiga with the highest exploitation of U3O8 has strongly acidic to slight alkaline water, which is the most contaminated. Mortórios with the lowest exploitation presents a higher contamination of slightly acidic to alkaline water than that of acidic to alkaline water from Mondego Sul, but the former has As (V), whereas the latter has As (III), which is toxic. The stream sediments from Mortórios present the lowest contamination, except for Th that has a higher median value than that from Vale de Abrutiga. Stream sediments from Mondego Sul have higher U, Th, Pb and lower Co, Cr, Cu and Zn median values than those of Vale de Abrutiga.
- Astraelenia Saomamedensis N. Sp. - a new gigantic rhynchonellid species and its palaeobiogeographical implications for the Portalegre syncline (Central Portugal)Publication . Schemm-Gregory, Mena; Piçarra, José Manuel
- Biostratigraphic and structural research of the Guedelhinha-Lançadoiras- Algaré sector of the Neves-Corvo mine region, Iberian Pyrite BeltPublication . Pereira, Zélia; Matos, João Xavier; Mendes, Márcia; Solá, A. Rita; Albardeiro, Luís; Morais, Igor; Araújo, Vítor; Pacheco, Nelson; Oliveira, José TomásABSTRACT: Based on drill hole sampling and sedimentary rock dating by palynology, the present research focuses on the palynostratigraphic events established in the key geological section of Guedelhinha-Lancadoiras-A lgare located in the Portuguese Neves-Corvo mine region, Iberian Pyrite Belt. The age data allow detailing the lithostratigraphic sequence and further understanding the complex structural setting, representing an important contribution to the geological knowledge of this sector located to the immediate WNW of the Neves-Corvo VMS deposit. The combination of the studied events allows the reconstruction of the Devonian-Carboniferous sedimentation and paleoenvironments along the Iberian Pyrite Belt. Several stratigraphic hiatuses identified in the Neves-Corvo region by the palynological record are con-firmed, mainly occurring from the mid Frasnian to mid Famennian, from the early and mid Strunian, and from the early to late Tournaisian, which were mainly coincident with the worldwide extinction events, in particular during Frasnian-Famennian and Late Devonian times. Extensional tectonics and related gravitational faults, local uplift mechanisms and intense volcanic activity could also explain the lack of palynological data and sedimentary hiatus. In this research, the importance of the late Strunian times in the Iberian Pyrite Belt (Miospore Biozone LN of the Neves Formation) is highlighted, confirming the contemporaneity of felsic volcanism, hydrothermalism, sulphide mineralization precipitation and black shale anoxic sedimentation.
- Cadomian magmatism and metamorphism at the Ossa Morena/Central Iberian zone boundary, Iberian Massif, Central Portugal: Geochemistry and P–T constraints of the Sardoal ComplexPublication . Henriques, S.B.A.; Neiva, A.M.R.; Tajcmanová, L.; Dunning, G. R.ABSTRACT: A well preserved Cadomian basement is exposed in the Iberian Massif, Central Portugal, at the Ossa Morena/Central Iberian zone boundary, which allows the determination of reliable geochemical data. A sequence of Cadomian and Variscan magmatic and tectonometamorphic events has been already described for this area and are documented in other areas of the Avalonian-Cadomian orogen. However, the geochemical information concerning the Cadomian basement for this area is still limited. We present whole rock geochemical and oxygen isotopic information to characterize the igneous protoliths of the Sardoal Complex, located within the Tomar-Badajoz-Cordoba Shear Zone, and identify their tectonic setting. We use detailed petrography, mineral chemistry and P-T data to characterize the final Cadomian tectonometamorphic event. The Sardoal Complex contains orthogneiss and amphibolite units. The protoliths of the orthogneiss are calc-alkaline magmas of acid composition and peraluminous character that were generated in an active continental margin in three different stages (ca. 692 Ma, ca. 569 Ma and ca. 548 Ma). The most significant processes in their petrogenesis are the partial melting of old metasedimentary and meta-igneous crust at different crustal levels and the crystal fractionation of plagioclase, alkali feldspars, apatite, zircon and Fe-Ti oxides. The protoliths of the amphibolite, older than ca. 540 Ma, are tholeiitic and calc-alkaline magmas of basic composition that display N-,T- and E-MORB affinities. They were generated in an active continental margin. Crustal contamination and fractional crystallization of hornblende and diopside were involved in their petrogenesis. However, the fractional crystallization was not significant. The magmatic activity recorded in the Sardoal Complex indicates the existence of a long-lived continental arc (ca. 692-540 Ma) with coeval felsic and mafic magmatism. The final stage of the Cadomian metamorphism is usually represented in other areas of the Cadomian basement as a LP-HT metamorphic event. However, the P-T data obtained by thermodynamic modelling indicates medium pressure/high temperature conditions at ca. 540 Ma. These data suggest that the Sardoal Complex represents a deeper level of the exhumed Cadomian basement where the final stage of the Cadomian metamorphism was recorded.
- Cadomian/Pan-African consolidation of the Iberian Massif assessed by its detrital and inherited zircon populations: is the similar to 610Ma age peak a persistent Cadomian magmatic inheritance or the key to unravel its Pan-African basement?Publication . Chichorro, Martim; Solá, A. Rita; Santos, Telmo M. Bento Dos; Amaral, Joao LainsABSTRACT: This work assessed the age distribution of Cadomian/Pan-African orogenic events (550-590 and 605-790Ma, respectively) in several zones of Iberian Massif by means of detrital and inherited zircon analysis compilation. Detrital zircon age spectra show that throughout the late Neoproterozoic-to-Early Ordovician era (similar to 120Ma sedimentary record), the main systematic peak occurs at similar to 610Ma, followed by peaks at typical Cadomian ages (similar to 590-550Ma). Inherited zircons incorporated in Cambrian-to-Lower Ordovician igneous rocks show typical Cadomian ages (similar to 590-550Ma) but, once again, a remarkably consistent Pan-African similar to 610Ma peak occurs. In accordance with compiled zircon data and taking into account the evidence of North African peri-cratonic inliers, Ediacaran (similar to 610Ma) zircons incorporated in Paleozoic magmas provide indirect evidence of Pan-African magmatism, suggesting that these magmas and synorogenic sediments are likely to constitute the cryptic stratigraphic infrastructure of most of the Iberian Massif. The main source of similar to 610Ma inherited zircons may be the lateral chrono-equivalents of the Saghro and Bou Salda-M'Gouna Groups (Anti-Atlas, Morocco) and/or coeval igneous rocks from West African Craton or Trans-Sahara Belt, emplaced at a stratigraphic level below the late-Ediacaran sediments of the Ossa Morena Zone and the Central Iberian Zone. Assuming that the Iberian crust is a fragment of the Pan-African orogen, a relative paleoposition situated between the West African Craton and the Trans-Saharan Belt during the Late Neoproterozoic is proposed. The closed-system behaviour of Stenian-Tonian detrital zircon ages in the Trans-Sahara Belt suggests that this mega-cordillera acted as a barrier, in paleogeographic terms, to separating the Sahara Metacraton from Iberia. In Iberia, the opening of the system to Stenian-Tonian detrital zircon during the Ordovician indicates that, at that time, the Trans-Saharan Belt had already become a vast peneplain, which favoured a large drainage system with a long-distance transport mechanism that fed the passive continental margins.
- Callovian (Middle Jurassic) dinoflagellate cysts from the Algarve Basin, southern PortugalPublication . Borges, Marisa; Riding, James B.; Fernandes, Paulo; Matos, Vasco; Pereira, Zélia
- Contrasting Ordovician high- and low-pressure metamorphism related to a microcontinent-arc collision in the Eastern Cordillera of Perú (Tarma province)Publication . Willner, Arne P.; Tassinari, Colombo C. G.; Rodrigues, José Feliciano; Acosta, Jorge; Castroviejo Bolíbar, Ricardo; Rivera, MiguelHigh-pressure conditions of 11–13 kbar/500–540 °C during maximum burial were derived for garnet amphibolite in the Tapo Ultramafic Massif in the Eastern Cordillera of Peru using a PT pseudosection approach. A Sm–Nd mineral-whole rock isochron at 465 ± 24 Ma dates fluid influx at peak temperatures of ~600 °C and the peak of high pressure metamorphism in a rodingite of this ultramafic complex. The Tapo Ultramafic Complex is interpreted as a relic of oceanic crust which was subducted and exhumed in a collision zone along a suture. It was buried under a metamorphic geotherm of 12–13 °C/km during collision of the Paracas microcontinent with an Ordovician arc in the Peruvian Eastern Cordillera. The Ordovician arc is represented by the western Marañon Complex. Here, low PT conditions at 2.4–2.6 kbar, 300–330 °C were estimated for a phyllite–greenschist assemblage representing a contrasting metamorphic geotherm of 32–40 °C/km characteristic for a magmatic arc environment.