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- Admissibility Grid to Support the Decision for the Preferential Routing of Portuguese Endogenous Waste Biomass for the Production of Biogas, Advanced Biofuels, Electricity and HeatPublication . Crujeira, Teresa; Trancoso, Maria Ascensão; Eusebio, Ana; Oliveira, Ana Cristina; Passarinho, Paula; Abreu, Mariana; Marques, Isabel Paula; Marques, Paula; Marques, Susana; Albergaria, Helena; Pinto, Filomena; Costa, Paula; Andre, Rui N.; Girio, Francisco; Moura, PatríciaABSTRACT: A methodology was developed to assess the allocation of different types of endogenous waste biomass to eight technologies for producing electricity, heat, biogas and advanced biofuels. It was based on the identification of key physicochemical parameters for each conversion process and the definition of limit values for each parameter, applied to two different matrices of waste biomass. This enabled the creation of one Admissibility Grid with target values per type of waste biomass and conversion technology, applicable to a decision process in the routing to energy production. The construction of the grid was based on the evaluation of 24 types of waste biomass, corresponding to 48 sets of samples tested, for which a detailed physicochemical characterization and an admissibility assessment were made. The samples were collected from Municipal Solid Waste treatment facilities, sewage sludges, agro-industrial companies, poultry farms, and pulp and paper industries. The conversion technologies and energy products considered were (trans)esterification to fatty acid methyl esters, anaerobic digestion to methane, fermentation to bioethanol, dark fermentation to biohydrogen, combustion to electricity and heat, gasification to syngas, and pyrolysis and hydrothermal liquefaction to bio-oils. The validation of the Admissibility Grid was based on the determination of conversion rates and product yields over 23 case studies that were selected according to the best combinations of waste biomass type versus technological solution and energy product.
- Evaluation of the potential of biomass to energy in Portugal : conclusions from the CONVERTE projectPublication . Abreu, Mariana; Reis, Alberto; Moura, Patrícia; Fernando, Ana Luisa; Luís, Gabriel; Quental, Lídia; Patinha, Pedro; Gírio, FranciscoABSTRACT: The main objective of the Portuguese project "CONVERTE-Biomass Potential for Energy" is to support the transition to a low-carbon economy, identifying biomass typologies in mainland Portugal, namely agri-forest waste, energy crops and microalgae. Therefore, the aim was to design and construct a georeferenced (mapping) database for mainland Portugal, to identify land availability for the implementation of energy crops and microalgae cultures, and to locate agricultural and forestry production areas (including their residues) with potential for sustainable exploitation for energy. The ArcGIS software was used as a Geographic Information System (GIS) tool, introducing the data corresponding to the type of soil, water needs and edaphoclimatic conditions in shapefile and raster data type, to assess the areas for the implantation of the biomass of interest. After analysing the data of interest in each map in ArcGIS, the intersection of all maps is presented, suggesting adequate areas and predicting biomass productions for the implementation of each culture in mainland Portugal. Under the conditions of the study, cardoon (72 kha, 1085 kt), paulownia (81 kha, 26 kt) and microalgae (29 kha, 1616 kt) presented the greater viability to be exploited as biomass to energy in degraded and marginal soils.
- Microalgae in a global world: New solutions for old problems?Publication . Vieira De Mendonça, Henrique; Assemany, Paula; Abreu, Mariana; De Aguiar Do Couto, Eduardo; Martins Maciel, Alyne; Duarte, Renata Lopes; Santos, Marcela Granato Barbosa dosABSTRACT: The human population blast has brought several problems related with the overconsumption of a wide range of feedstocks and natural resources conducting to their risk of depletion. The consumption of fossil fuels is an example, with increasing levels of exploitation and negative impacts caused by their use. Anthropogenic activities have triggered the over accumulation of many hazardous substances and wastes which are regarded to be detrimental to life in the Earth and to the various planet ecosystems. There is an urgent need to restore natural resources and unwanted residues and wastes to levels prior the demographic explosion. Microalgal biotechnology appears to be pivotal to achieve this goal in a near future to come. This review presents the current resource problems affecting the Earth and how microalgae are expected to be an important part of the solution, discussing how the production of renewable energy from microalgae can help in an integrated way to mitigate different environmental problems. Microalgae are able to convert wastewaters, CO2 and organic residues in marketable biomass for different uses, including biofuels, converting waste in value. An inventory of current microalgal-based biorefineries in operation as well as a directory of companies, products and applications are also presented.
- Marginal soils for bioenergy production : How to identify these soils in Portugal?Publication . Abreu, Mariana; Reis, Alberto; Fernando, Ana LuisaABSTRACT: n the bioenergy/biorefineries sector, energy crops have achieved a relevant position as a feedstock for bio-based products, biofuels and bioenergy. To produce the energy crops, soils with low Indirect Land Use Change (ILUC) risk must be utilized, such as marginal/degraded/contaminated (MDC) soils. Locating these types of soils in any territory, region, or country is challenging. Several criteria, e.g. soil drainage, dryness, temperature, have been identified by the European Union, and allow to classify soils as marginal. Yet, the dispersed information makes the identification and selection of marginal soils a challenging process. Therefore, this study details the tools and baseline documents that can be used to identify marginal areas, presenting low ILUC risk for the cultivation of energy crops. The application of the methodology to Continental Portugal allowed to obtain a preliminary map that indicates available soils for the cultivation of energy crops.
- Estimativa de potenciais técnicos de energia renovável em Portugal: eólico, solar fotovoltaico, solar concentrado, biomassa e oceanosPublication . Simoes, Sofia; Simões, Teresa; Barbosa, Juliana; Rodrigues, Carlos; Azevedo, Pedro; Cardoso, João P.; Facão, Jorge; Costa, Paula Silva; Justino, Paulo Alexandre; Gírio, Francisco; Reis, Alberto; Passarinho, Paula; Duarte, Luís C.; Moura, Patrícia; Abreu, Mariana; Estanqueiro, Ana; Couto, António; Oliveira, Paula; Quental, Lídia; Patinha, Pedro; Catarino, Justina; Picado, AnaExecutive Summary: There is a clear need to accelerate the energy transition, including the implementation of renewable electricity production plants, as well as the increase in consumption of other renewable energy carriers in buildings, industry, transport and other sectors. This work provides key information to make this transition possible, that is, the technical renewable energy potentials for Portugal. The aim is thus to contribute to policy support, as well as to decision-making by various Portuguese stakeholders (public and private) in the domains of energy, energy transition and greenhouse gases emissions mitigation. The work presents the technical renewable energy potentials for Portugal to: (i) decentralized solar photovoltaic (PV) plants in artificialized (or built-up) areas; (ii) centralized solar PV plants in non-artificialized (or natural) areas; (iii) concentrated solar power; (iv) onshore wind; (v) offshore wind (floating and fixed); (vi) bioenergy, and (vii) solar thermal. The wave energy primary energy resource potential is also presented (not the technical potential). The technical potential values of renewable energy sources (RES) presented are dynamic values, given the substantial uncertainty associated with their estimation. The study identifies technical RES potentials i.e., the technically viable energy generation achievable from a specific technology, considering the primary energy resource available and the geographic, environmental and land use limitations. RES economic potentials represent the fraction of RES technical potential that is economically viable, but they are not presented in this work. Likewise, this report does not address market potential, that translate the capacity and energy generation that the market effectively manages to implement. The presented RES technical potentials include the total capacity currently installed in the country. The technical potentials are estimated mostly for mainland Portugal, in most cases with a spatial disaggregation of at least NUT2 and sometimes for NUT5 and/or type of building. Despite adopting an approach based on a territorial analysis in which some areas of the country are excluded, this potential does not correspond to the work done in mapping less-sensitive areas towards future definition of RES “Go-To Areas”. The decentralized solar PV potential in artificialized areas is divided into 6 area types: industrial areas; commercial buildings; residential and mixed-use buildings; villas; health, education, cultural, tourist and military buildings, and other land uses (including parking lots and patios, ports, waste and wastewater treatment infrastructure, sports facilities, among others). It is estimated a technical potential of 23.33 GW that could generate up to 36.84 TWh/year. This potential is distributed throughout the entire territory of mainland Portugal but is higher in the North and Center regions. The RES technical potential for centralized solar PV was estimated as a range of values that translate the uncertainty associated with using different levels of concern in excluding certain areas in which solar PV can be deployed (for example to safeguard ecosystems, water resources, agriculture or archaeological heritage). The centralized solar PV potential varies between 168.82 GW and 45.63 GW. The maximum threshold of installed capacity could generate 278.11 TWh/year of electricity. The value is high and reflects on the one hand, the excellence of the solar resource throughout the country, and on the other, the large size of the considered areas. The CSP potential is 62.6 GW with a corresponding electrical production potential of 183.61 TWh/year. It is mainly located in the Alentejo region, although other areas have also been identified in other regions of the country. The wind onshore technical potential is 15.7 GW, that could generate 37.13 TWh/year, taking into account the safeguarding of various areas for the protection of ecosystems and also social acceptability issues. In the case of offshore wind and considering a capacity density of 4 MW/km2 for floating offshore and 5.5 MW/km2 for fixed offshore, a total of 36 GW and 2 GW are obtained, respectively. This capacity could generate up to 126.14 TWh/year (floating offshore) or 6.31 TWh/year (fixed offshore). The solar thermal energy potential focused residential and service buildings (such as nursing homes, barracks, etc., tourism, hospitals, indoor swimming pools and other sports facilities). The potential is of 0.95 GWt and 0.95 TWh/year for service buildings, 7.26 GWt and 5.84 TWh/year for residential buildings. For industry there is a potential of 1.06 GWt, which could generate up to 1.15 TWh/year for applications up to 160 ºC. The total technical potential of solar thermal is 9.25 GWt and 7.93 TWh/year of thermal energy generated, with a substantial weight of residential buildings in the total value. Potential values are disaggregated by NUTS III and type of building. In terms of biomass and bioenergy potential, annual values of forest biomass, agricultural biomass, agro-industrial waste, urban waste and wastewater treatment are estimated, totaling around 58 TWh/year. Regarding the production of biofuels (HVO and FAME) it is estimated that the annual production of domestic used oils and other similar residues is 1.4 TWh/year. The use of oils from food crops such as soybean, sunflower and rapeseed is limited by European (and national) policy guidelines and is 2.1 TWh/year. Regarding wave energy, the resource potential is estimated between 1.4 GW for 80 m bathymetry and 4.8 for 20 m bathymetry. There are substantial uncertainties associated with the presented values, inherent to the methodological approach considered. Nevertheless, these estimates are a valuable starting point to be refined and improved in subsequent updates.
- Microalgae biomass production for biofuels in brazilian scenario : a critical reviewPublication . Santos, Marcela Granato Barbosa dos; Duarte, Renata Lopes; Martins Maciel, Alyne; Abreu, Mariana; Reis, Alberto; Mendonca, Henrique Vieira deABSTRACT: The Brazilian environmental, economic, and social conditions for the long-term establishment of mass culture of microalgae for either biofuel production or greenhouse gases (GHG) abatement are described in detail. A brief historical introduction of the microalgal biotechnology is presented followed by a compilation of Brazilian published research works on microalgae, with special emphasis on microalgal Brazilian biodiversity and applied phycology. Several case studies on Brazilian microalgal biorefineries are presented with special emphasis on wastewater (WW) treatment. The manuscript also adds valuable new information about which regions of the country offer better growing conditions for dozens of endemic species. Favorable climatic and environmental conditions for the cultivation of several microalgae (green) and cyanobacteria species in specific regions of the country are suggested. Finally, based on realistic biomass productivities and product yields for the Brazilian context, several scenarios for biofuel production and/or carbon dioxide (CO2) abatement have been designed, and results are presented and critically discussed. Brazilian self-sufficiency on either fuels for transportation or GHG abatement using exclusively microalgae is quite challenging but achievable accordingly with the present state of the art.
- Analytical protocol for the characterization of solid organic fractions: contribution for the biochemical and thermochemical potential assessment of biomass [Poster]Publication . Trancoso, Maria Ascensão; Crujeira, Teresa; Sousa, R.; Calisto, Sandra C.; Branco, J.; Oliveira, Ana Cristina; Passarinho, Paula; Abreu, Mariana; Moura, Patrícia; Gírio, FranciscoABSTRACT: In the scope of the CONVERTE project an optimised and uniformed methodology was developed in order to better evaluate the use of endogenous biomasses for energy production by biochemical or thermochemical processes. A protocol for preparation and characterization was designed and validated by the use of biomass certified reference materials and quality control actions. Extensive analytical work was performed and the results were summarized in accordance with their relevance for either biochemical or thermochemical processes.
- Infraestrutura de investigação para a biomassa e a bioenergia: BBRI - Biomass and Bioenergy Research InfrastructurePublication . Reis, Alberto; Abreu, Mariana; Pacheco, Marta; Bernardo, Joana; Silva, R.; Domingues, Lucília; Teixeira, J.A.; Gírio, FranciscoRESUMO: A BBRI é a única Infraestrutura Nacional de Investigação em Biomassa e Bioenergia, que integra o Roteiro Nacional de Infraestruturas de Investigação de Interesse Estratégico em Portugal desde 2014, sendo distribuída por dois nós. O nó de Lisboa tem por base as infraestruturas laboratoriais e piloto existentes na Unidade de Bioenergia e Biorrefinarias (UBB) do Laboratório Nacional de Energia e Geologia (LNEG) e o nó de Braga, as infraestruturas laboratoriais e tecnológicas do Centro de Engenharia Biológica (CEB) da Universidade do Minho (UM). As atividades científicas da BBRI estão focadas nas tecnologias de conversão de biomassa para obtenção de biocombustíveis avançados, produtos não-energéticos de base biológica e outros biomateriais, inseridas em seis sub-plataformas de investigação (sub-RIs). O trabalho da BBRI nestas 6 sub-RIs encontra-se complementarmente organizado em atividades de formação, serviços e atividades de disseminação, visando a capacitação de novos profissionais em bioenergia sustentável e contribuindo para a excelência da investigação em Portugal no domínio da Bioenergia e Bioeconomia.
- Sustainable value methodology to compare the performance of conversion technologies for the production of electricity and heat, energy vectors and biofuels from waste biomassPublication . Moura, Patrícia; Henriques, José João M. Silva; Alexandre, Jorge; Oliveira, Ana Cristina; Abreu, Mariana; Gírio, Francisco; Catarino, JustinaABSTRACT: The Sustainable Value methodology was used to compare and rank eight combinations of waste biomass types and conversion technologies on a common assessment basis to produce energy, energy vectors and advanced biofuels. The studied combinations included agricultural and agro-industrial residues, slurries and effluents, pulp and paper mill sludge, piggery effluents and organic fractions of municipal solid waste, to produce biodiesel by (trans)esterification, biogas by anaerobic digestion, ethanol by fermentation, hydrogen by dark fermentation, electricity and heat by combustion, biogas and synthesis gas by gasification, and bio-oils by pyrolysis or hydrothermal liquefaction. The numerator “Functional Performance” of the Sustainable Value indicator was estimated according to 14 criteria of process technology, material and energy inputs and outputs, and acceptance by the stakeholders. The performance of the technologies was classified based on the values of relative importance (φ) and level of satisfaction (S) attributed to each criterion. The gasification of residues from the olive-oil industry reached the highest “Functional Performance”, followed by anaerobic digestion of chestnut processing residues and pig-rearing effluents. The Sustainable Value denominator “Costs” depended mainly on the degree of maturity of the technologies, which penalised pyrolysis, hydrothermal liquefaction and dark fermentation. The final ranking of the Sustainable Value indicator was gasification> combustion> anaerobic digestion> (trans)esterification> pyrolysis and fermentation to ethanol> hydrothermal liquefaction> dark fermentation, respectively for the most adequate waste biomass types under study. Thermochemical conversions were mainly impacted by process and input criteria, while output and social acceptance criteria were more decisive for the biochemical conversions.
- The CONVERTE project: biomass potential for energyPublication . Abreu, Mariana; Moura, Patrícia; Reis, Alberto; Eusebio, Ana; Oliveira, Ana Cristina; Pinto, Filomena; Alexandre, Jorge; Silva, Luís; Trancoso, Maria Ascensão; Gírio, FranciscoABSTRACT: Climate change caused by the excessive use of non-renewable resources as a means of supporting the current society demands is forcing the development of circular economy models and social, economic and environmental balanced solutions. In Portugal, in recent decades, important progresses have been made on waste resources management practices in line with the objectives and directives of the European Union. The urban and industrial wastes are, to a certain extent, a case of success since the effort developed has created tools for the prevention, control, recovery and recycling of a considerable percentage of the generated amounts. However, this effort has not yet reached its full potential, and there are still diverse underexplored issues, such as a systematic assessment of the waste biomass suitability for specific energy conversion technologies, and the promotion of non-food-competing energy crops on marginal lands. CONVERTE will identify and quantify the different waste biomass types generated in the Portuguese continental territory, and shall develop a biomass-driven energy matrix that correlates the biomass types with eight technological value chains for heat, power and/or advanced biofuels as main products. This is expected to impact positively on the national energy security and to reduce the overall Portuguese greenhouse gas (GHG) emissions, namely in the transport sector, contributing to increase the country sustainability score.